Solar Energy Materials and Solar Cells, Vol.100, 246-250, 2012
Poor man's green bulk heterojunction photocells: A chlorine-free solvent for poly(3-hexylthiophene)/C-60 composites
Although C-60 is unquestionably not only the cheapest but also the most energy-saving fullerene, lack of suitable solvent to make bulk heterojunction composites with it has prevented its use in photocells. Here, it is shown that a not-so-common organic solvent 1,2,4-trimethylbenzene (TMB) is useful to prepare cost-effective bulk heterojunction composites based on C-60. Additionally, chlorine-free TMB is expected to be environmental friendly compared with chloroaromatic solvents commonly used for the preparation of polymer/fullerene composites. A preliminary evaluation indicated that a poly(3-hexylthiophene) (P3HT)/C-60 bulk heterojunction photocell prepared from TMB solution shows power conversion efficiency comparable to that of a P3HT/PCBM photocell, suggesting that C-60 should be revisited as a promising candidate for an acceptor material in polymer bulk heterojunction composites for low-cost green photocells. (C) 2012 Elsevier B.V. All rights reserved.