화학공학소재연구정보센터
Solar Energy Materials and Solar Cells, Vol.109, 199-203, 2013
Influence of emitter bandgap on interdigitated point contact back heterojunction (a-Si:H/c-Si) solar cell performance
We report on the theoretical investigation of a silicon-based interdigitated back contact back heterojunction (BHJ) solar cell that combines the advantages of heterojunction with intrinsic thin layer (HIT) solar cell and point contact back junction c-Si solar cell. Our results show an optimum bandgap for emitter (p-type a-Si:H) layer for this cell to be approximately 1.72 eV. As we increase the bandgap from 1.3 eV to 2.2 eV, the open circuit voltage (V-oc) increases from 0.45 V to 0.75 V and then saturates, while the short circuit current density (J(sc)) remains constant at 35 mA/cm(2) up to about 2.0 eV, and then decreases to zero. Fill factor (FF) increases from 57% to a maximum of 75% as the bandgap increases from 1.3 eV to similar to 1.72 eV, respectively, and then decrease to 5% when the bandgap reaches 2.1 eV. Efficiency increases from 7% and reaches a maximum of about 19% at around 1.7 eV and then decreases to zero at 2.1 eV. These results can be correlated to changes in valance band spike (barrier) when emitter bandgap increases from 1.3 eV to 2.2 eV, and are explained in terms of band alignment between p-a-Si:H/i-a-Si:H/n-type-c-Si. (C) 2012 Elsevier B.V. All rights reserved,