Solar Energy Materials and Solar Cells, Vol.117, 494-498, 2013
VO2-based smart coatings with improved emittance-switching properties for an energy-efficient near room-temperature thermal control of spacecrafts
One of the major challenges facing the use of thermochromic coatings as efficient Smart Radiator Devices (SRDs) for a passive energy-efficient thermal control of spacecrafts is the limited high temperature emittance that can be achieved with present devices. Through an elegant choice of the thickness of an SiO2 layer being part of a VO2-based SRD multilayer structure, we obtained an emittance as high as 0.80 at high temperature, while maintaining a large emittance tunability. More interestingly, by doping VO2 with tungsten (W), the transition temperature of pure VO2 occurring originally at about 68 C could be decreased down to about 19.5 degrees C with 2.9 at% of W. The average decrease rate of the transition temperature was found to be similar to 16.5 degrees C per 1 at% of W. This reduction was accompanied by a displacement of the emittance transition region that can be tailored over a wide range of temperatures, and by a shrinking of the hysteresis width. This work constitutes an important breakthrough toward practical applications of thermochromic VO2-based smart coatings for passive energy-efficient thermal control of spacecrafts close to room temperature.(C) 2013 Elsevier B.V. All rights reserved.
Keywords:Thermochromic VO2;W doping;Smart thermal window;Smart radiator device;Space vehicle;Energy efficiency