A series of solution-processed small molecular solar cells (SMSCs) were fabricated with 2,4-bis[4-(N,N-diisobutylamino)-2,6-dihydroxyphenyl] (DIB-SQ) and [6,61-phenyl-C-71-butyric acid methyl ester (PC71BM) as the active layer. The cells with MoO3 as anode interfacial layer and LiF as cathode interfacial layer have the maximum power conversion efficiency (PCE) 2.68%, with short circuit density (J(sc)) of 8.2 mA/cm(2), open circuit voltage (V-oc) of 0.9 V and fill factor (FF) of 363% under 100 mW/cm(2) illumination intensity. The key parameters, including J(sc) V-oc, and FF of cells with MoO3 as anode interfacial layer and LiF as cathode interfacial layer, are improved about 54.7%, 26.9%, and 23.5% compared with these of cells using PEDOT:PSS as anode interfacial layer and LiF as cathode interfacial layer. The underlying reasons are mainly attributed to the effect of MoO3 layer on charge carrier collection and morphology of active layer. The effect of illumination intensity on the performance of cells was also discussed in detailed. (C) 2013 Elsevier B.V. All rights reserved.