Expanded graphite (EG) powder as a typical porous material has high thermal conductivity and large surface area that are often used to enhance the thermal conductivity of phase change materials (PCMs). Ten composites of paraffin/EG powder with various weight fractions were elaborated by high pressure compression. Their microstructure configuration and thermal properties were characterized with Scanning Electron Microscopy (SEM), Thermal Constant Analyzer. The saturation sorption capacity of EG under compression was experimentally determined. The thermal conductivity of the paraffin/EG composite is greatly enhanced by 41 times in maximum as compared to pure paraffin. Based on the experimental quantification, we propose a novel two-level scale model from micro-scale to macro-scale to compute the thermal conductivity of the composite. The numerical results agree well with the experimental data that validate the precision and reliability of the proposed model. Furthermore, the results reveal that both keeping porous EG structure at original morphology and increasing the saturated sorption capacity of paraffin in EG could eventually improve the heat transfer capacity of the composites. In addition, the proposed model would require more experimental validation based on the composites with different materials in future work. (C) 2014 Elsevier B.V. All rights reserved.