Solar energy can potentially play a very important role in providing most of the heating, cooling and electricity needs of the world. With the emergence of solar photocatalytic detoxification technology, solar energy also has the potential to solve our environmental problems. However, we do not see widespread commercial use of solar energy. Some of the emerging developments in solar may change that situation. This paper describes some of the new and emerging developments, with special emphasis on: (1) nanoscale antennas for direct conversion of sunlight to electricity with potential conversion efficiencies approaching 80-90%; (2) new thermodynamic cycles for solar thermal power, that have the potential to reduce capital costs by 50%; and (3) solar photocatalytic oxidation for cleanup of industrial wastewater, drinking water, soil and air. The paper describes the fundamentals of each of these developments, their potential, present status and future opportunities for research. (1) Nanoscale antenna solar energy conversion: The current photovoltaic technologies rely on the quantum nature of light and semiconductors which are fundamentally limited by the band-gap energies. A revolutionary new approach suggested by Professor Robert Bailey in 1972 revolves around the wave nature of light. Professor Bailey suggested that broadband rectifying antennas could be used for solar to d.c. conversion. These rectennas would not have the fundamental limitation of semiconductor band-gap limiting their conversion efficiencies. Rectennas for solar conversion would have dimensions of the order of the wavelengths of solar radiation which falls mostly in the sub-micron range. The challenges in actually achieving the objectives are many. This paper describes the challenges and approaches to their solution. (2) New thermodynamic cycles for solar thermal power: It is recognized that the capital costs of solar thermal power will have to be reduced by about 50% in the near future in order to make it competitive with fossil fuels (especially natural gas) based power systems. Potential exists for meeting this goal by reducing the costs and improving the thermodynamic performance of power cycles by hybridization and combined cycle approaches and by employing new and innovative ideas in thermal power cycles. This paper describes the new thermodynamic approaches with an emphasis on an innovative new thermodynamic cycle using ammonia and water mixtures as the working fluids. (3) Solar photocatalytic detoxification and disinfection of water and air: Although the potential of solar radiation for disinfection and environmental mitigation has been known for years, only recently has this technology been scientifically recognized and researched. Solar photocatalytic oxidation has been demonstrated to effectively treat groundwater, drinking water, and industrial wastewater. In some applications such as decoloration and reduction of COD it may be the only effective method of treatment. Treatment of indoor air by the photocatalytic method has been demonstrated as the most effective technology for that application. This paper describes the recent developments and identify challenges and future research opportunities. (C) 2003 Elsevier Ltd. All rights reserved.