In the recent years, cadmium chalcogenide compounds have been extensively investigated because of their potential applications in solar energy conversion. Thin films of CdSe have been deposited onto the stainless steel and fluorine doped tin oxide (FTO) coated glass Substrates using simple and inexpensive electrodeposition technique. The non-aqueous solvent ethylene glycol (CH2OHCH2OH) containing precursors of Cd and Se with ethylenediaminetetraacetic acid (EDTA) tetra sodium salt as a complexing agent is used to obtain stoichiometric deposits. Deposition potential was estimated from polarization Curves and other preparative parameters such as bath temperature and concentration of solution were optimized. X-ray diffraction (XRD) analysis reveals that the films are polycrystalline with cubic structure. PEC study shows the CdSe films are photoactive. Optical absorption study shows the presence of direct transition with band gap energy 1.72 eV. The energy dispersive analysis by X-rays (EDAX) reveals that the substrate is well covered with large number of grains indicating compact structure. The average ratio of the atomic percentage of Cd:Se is 50.31:49.69, showing that the deposited films are almost stoichiometric. (c) 2005 Elsevier Ltd. All rights reserved.