화학공학소재연구정보센터
홈 로그인 로그아웃 연락처 사이트맵
Applied Chemistry for Engineering, Vol.25, No.5, 487-496, October, 2014
Export Citation
Phenothiazine과 2,1,3-Benzothiadiazole을 포함한 Copolymer의 합성 및 Side-chain 치환에 따른 Photovoltaic 특성 연구
Synthesis, Photovoltaic Properties and Side-chain Effect of Copolymer Containing Phenothiazine and 2,1,3-Benzothiadiazole
윤대희, 유한솔, 성기호, 임정호, 박용성, 우제완†
  • 상명대학교 공업화학과
Dae-Hee Yun, Han-Sol Yoo, Ki-Ho Seong, Jeong-Ho Lim, Yong-Sung Park, and Je-Wan Woo†
  • Industrial Chemistry, Sangmyung University, Honggi-Dong 7, Jongno-Gu, Seoul, 110-743, Republic of Korea
E-mail:
초록
본 연구에서는 phenothiazine과 benzothiadiazole을 기반으로 하고, phenothiazine의 질소 위치에 다양한 side-chain을 치환한 고분자를 합성하였다. 합성된 고분자는 광학적, 전기화학적 분석 결과 300~700 nm에서 흡수를 보였고, -5.4 eV 정도의 이상적인 HOMO energy level를 갖는 특성을 확인하였다. 고분자와 PC71BM을 광활성층으로 사용한 소자를 제작하였고, 측정결과 branched side-chain을 가지며 탄소수가 많은 P2HDPZ-bTP-OBT가 2.4%로 최대 광전변환효율을 갖는 것으로 확인되었다 (VOC : 0.74 V, JSC : 6.9 mA/cm2, FF : 48.0%).
In this study, three kinds of polymers based on phenothiazine-benzothiadiazole were synthesized by a Suzuki coupling reaction, and the various side-chains were substituted at the nitrogen of phenothiazine. The optical and electrochemical properties of synthesized polymers were analyzed. The results indicate that their absorption ranged from 300 to 700 nm, and also confirmed the ideal highest occupied molecular orbital (HOMO) energy level was about -5.4 eV with low band-gap energy. Photovoltaic devices were fabricated using a photoactive layer composed of a blended solution of the polymer and PC71BM in ortho-dichlorobenzene The device with P2HDPZ-bTP-OBT containing the branched side-chain and long chain showed the best performance; the maximum power conversion efficiency of this device was 2.4% (with VOC : 0.74 V, JSC : 6.9 mA/cm2, FF : 48.0%).
Keywords:Phenothiazine derivative;Benzothiadiazole derivative;Organic photovoltaics (OPVs);Suzuki coupling;Push-pull structure
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