화학공학소재연구정보센터
홈 로그인 로그아웃 연락처 사이트맵
Journal of Industrial and Engineering Chemistry, Vol.20, No.5, 2671-2679, September, 2014
DOI10.1016/j.jiec.2013.10.054  Export Citation
Transport and retention of polymer-stabilized zero-valent iron nanoparticles in saturated porous media: Effects of initial particle concentration and ionic strength
A. Ramazanpour Esfahani, A. Farrokhian Firouzi†, Gh. Sayyad, and A.R. Kiasat1
  • Department of Soil Science, Faculty of Agriculture, Shahid Chamran University, Ahvaz, Iran
  • 1Department of Pure Chemistry, Faculty of Science, Shahid Chamran University, Ahvaz, Iran
E-mail:
This study investigated the transport and retention of polyacrylic acid and polyvinylpyrrolidone stabilized zero-valent iron nanoparticles (PAA-ZVIN and PVP-ZVIN) in saturated porous media. The transport experiments were conducted in sand packed columns. The breakthrough curves (BTCs) and retention curves of ZVIN were analyzed. Results of transport experiments showed that increasing initial particle concentration and ionic strength led to a decrease in ZVIN transport. The zeta potentials and hydrodynamic diameters of PAA-ZVIN were apparently more negative compared to PVP-ZVIN. Results indicated that some mechanisms such as aggregation, ripening, and surface roughness had considerable impact on ZVIN retention in porous media.
Keywords:Zero-valent iron nanoparticles;Porous media;Transport;Retention;Breakthrough curves
  1. Kassaee MZ, Motamedi E, Mikhak A, Rahnemaie R, Chem. Eng. J., 166(2), 490 (2011)
  2. Liu L, Wei SQ, Liu Y, Shao ZC, Desalination, 285, 271 (2012)
  3. Satapanajaru T, Chompuchan C, Suntornchot P, Pengthamkeerati P, Desalination, 266(1-3), 218 (2011)
  4. Chen JH, Qiu XQ, Fang ZQ, Yang M, Pokeung T, Gu FL, Cheng W, Lan BY, Chem. Eng. J., 181, 113 (2012)
  5. Mamindy-Pajany Y, Hurel C, Marmier N, Romeo M, Desalination, 281, 93 (2012)
  6. Lien HL, Zhang WX, J. Environ. Eng., 125, 1042 (1999)
  7. Liu Y, Majetich SA, Tilton RD, Sholl DS, Lowry GV, Environ. Sci. Technol., 39, 1338 (2005)
  8. Elliott DW, Zhang WX, Environ. Sci. Technol., 35, 4922 (2001)
  9. Saleh N, Sirk K, Liu Y, Phenrat T, Dufour B, Matyaszewski K, Tilton RD, Lowry GV, Environ. Eng. Sci., 24, 45 (2007)
  10. Zhang WZ, Daniel WE, Remediation. J., 16, 7 (2006)
  11. He F, Zhao DY, Liu JC, Roberts CB, Ind. Eng. Chem. Res., 46(1), 29 (2007)
  12. Kanel SR, Goswami RR, Clement TP, Barnett MO, Zhao D, Environ. Sci. Technol., 42, 896 (2008)
  13. He F, Zhao D, Environ. Sci. Technol., 39, 3314 (2005)
  14. Jiemvarangkul P, Zhang WX, Lien HL, Chem. Eng. J., 170(2-3), 482 (2011)
  15. Dong TT, Luo HJ, Wang YP, Hu BJ, Chen H, Desalination, 271(1-3), 11 (2011)
  16. Alidokht L, Khataee AR, Reyhanitabar A, Oustan S, Desalination, 270(1-3), 105 (2011)
  17. Sun TP, Li XQ, Zhang WX, Wang HP, Colloid Surf. A, 308, 60 (2007)
  18. Cosgrove T, Colloid science.principle, methods, and applications, Blackwell, Oxford, 2005p. 50.
  19. Schrick B, Hydutsky BW, Blough JL, Mallouk TE, Chem. Mater., 16, 2187 (2004)
  20. Raychoudhury T, Naja G, Ghoshal S, J. Contam. Hydrol., 118, 143 (2010)
  21. Phenrat T, Kim H, Fagerlund F, Ilangasekare T, Tilton R, Lowry GV, Environ. Sci. Technol., 43, 5079 (2009)
  22. Tiraferri A, Sethi R, J. Nanopart. Res., 11, 635 (2009)
  23. Tian YA, Gao B, Ziegler KJ, J. Hazard. Mater., 186(2-3), 1766 (2011)
  24. Kanel SR, Choi H, Water Sci. Technol., 55, 157 (2007)
  25. Saleh N, Kim H, Phenrat T, Matyjaszewski K, Tilton RD, Lowry GV, Environ. Sci. Technol., 42, 3349 (2008)
  26. Kim HJ, Phenrat T, Tilton RD, Lowry GV, J. Colloid Interface Sci., 370, 1 (2012)
  27. Pelley AJ, Tufenkji N, J. Colloid Interface Sci., 321(1), 74 (2008)
  28. Liu YQ, Choil H, Dionysiou D, Lowry GV, Chem. Mater., 17, 5315 (2005)
  29. Litton GM, Olson TM, Colloid Surf A, 107, 273 (1996)
  30. Johnson PR, Sun N, Elimelech M, Environ. Sci. Technol., 30, 3284 (1996)
  31. Sachoulchaicharoen N, O’Carrol DM, Herrera JE, J. Contam. Hydrol., 118, 117 (2010)
  32. Phenrat T, Saleh N, Sirk K, Kim HJ, Tilton RD, Lowry GV, J. Nanopart. Res., 10, 795 (2008)
  33. He F, Zhao D, Environ. Sci. Technol., 41, 6216 (2007)
  34. Sun YP, Li XQ, Cao JS, Zhang WX, Wang HP, Adv. Colloid Interface Sci., 120, 47 (2006)
  35. Phenrat T, Saleh N, Sirk K, Tilton RD, Lowry GV, Environ. Sci. Technol., 41, 284 (2007)
  36. Hosseini SM, Tosco T, Water Res., 47, 326 (2012)
  37. Bradford SA, Yates SR, Bettahar M, Water Resour. Res., 38, 1327 (2002)
  38. Bradford SA, Simunek J, Bettahar M, van Genuchten MT, Yates SR, Environ. Sci. Technol., 37, 2242 (2003)
  39. Tufenkji N, Miller GF, Ryan JN, Harvey RW, Elimelch M, Environ. Sci. Technol., 38, 5932 (2004)
  40. Bradford SA, Bettahar M, J. Contam. Hydrol., 89, 99 (2006)
  41. Tong M, Ma H, Johnson WP, Environ. Sci. Technol., 42, 2826 (2008)
  42. Liu D, Johnson PR, Elimelech M, Environ. Sci. Technol., 29, 2963 (1995)
  43. Tosco T, Sethi R, Environ. Sci. Technol., 44, 9062 (2010)
  44. Brant JM, Lecoanet H, Wiesner MR, J. Nanopart. Res., 7, 545 (2005)
  45. Wang Y, Li Y, Fortner JD, Hughes JB, Abriola LM, Pennell KD, Environ. Sci. Technol., 42, 3588 (2008)
  46. Wang Y, Li Y, Pennell KD, Environ. Toxicol. Chem., 27, 1867 (2008)
  47. ELIMELECH M, J. Colloid Interface Sci., 164(1), 190 (1994)
  48. Ben-mushe T, Dror I, Berkowitz B, Chemosphere, 81, 387 (2010)
  49. Bradford S, Torkzaban S, Walker S, Water Res., 41, 3012 (2007)
  50. Yao KM, Habibian MT, O’melia CR, Environ. Sci. Technol., 5, 1105 (1971)
  51. Wang DJ, Bradford SA, Harvey RW, Hao XZ, Zhou DM, J. Hazard. Mater., 229, 170 (2012)
  52. Gargiulo G, Bradford S, Simunek J, Ustohal P, Vereeken H, Klumpp E, Contam J, J. Contam. Hydrol, 92, 225 (2007)
  53. Shellenberger K, Logan BE, Environ. Sci. Technol., 36, 184 (2001)
  54. Chen KL, Elimelech M, Langmuir, 22(26), 10994 (2006)
  55. Chen KL, Elimelech M, J. Colloid Interface Sci., 309(1), 126 (2007)
  56. Yoon JS, Germaine JT, Culligan PJ, Water Resour. Res. 42, http://dx.doi.org/10.1029/2004WR003660. (2006)
  57. Kocur CM, O’Carrol DM, Sleep BM, J. Contam. Hydrol., 145, 17 (2013)
  58. Rosicka D, Sembera J, Nanoscale. Res. Lett., 6, 10 (2011)
  59. Taneda S, J. Phys. Soc. Jpn., 46, 1935 (1979)
  60. Torkzaban S, Kim HN, Simunek J, Bradford SA, Environ. Sci. Technol., 44, 1662 (2010)
  61. Vaidyanathan R, Tien C, Chem. Eng. Sci., 43, 289 (1988)
  62. Wang D, Paradelo M, Bradford SA, Peijenburg WJGM, Chu L, Zhu D, Water Res., 45, 5905 (2011)