화학공학소재연구정보센터
홈 로그인 로그아웃 연락처 사이트맵
Journal of Industrial and Engineering Chemistry, Vol.20, No.5, 3217-3227, September, 2014
DOI10.1016/j.jiec.2013.12.002  Export Citation
Silybum marianum extract as a natural source inhibitor for 304 stainless steel corrosion in 1.0 M HCl
N. Soltani†, N. Tavakkoli, M. Khayat Kashani1, A. Mosavizadeh, E.E. Oguzie2, and M.R. Jalali3
  • Department of Chemistry, Payame Noor University (PNU), Tehran 19395-4697, Islamic Republic of Iran
  • 1Department of Analytical Chemistry, Faculty of Chemistry, University of Kashan, Kashan, Islamic Republic of Iran
  • 2Electrochemistry and Materials Science Research Laboratory, Department of Chemistry, Federal University of Technology Owerri, PMB 1526, Owerri, Nigeria
  • 3Department of Physics, Payame Noor University (PNU), Tehran 19395-4697, Islamic Republic of Iran
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The use of Silybum marianum leaves extract as a 304 stainless steel corrosion inhibitor in 1.0 M HCl solution was investigated by weight loss measurements, potentiodynamic polarization and electrochemical impedance spectroscopy (EIS) methods. Potentiodynamic polarization curves indicated that S. marianum extract behaves as mixed-type inhibitor. The adsorption of the extract constituents was further discussed in view of Langmuir adsorption isotherm. The effect of temperature on the inhibition efficiency was studied. Quantum chemical parameters were also calculated, which provided reasonable theoretical explanation for the adsorption and inhibition behavior of S. marianum extract on the 304 stainless steel.
Keywords:Corrosion inhibition;Silybum marianum extract;304 stainless steel;Hydrochloric acid
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