A simple composite of foamed porous copper (FPCu) and ammonium perchlorate (AP) was prepared by filling AP into FPCu via solvent evaporation method. FPCu was prepared by galvanostatic electrodeposition. FESEM images showed that FPCu was structured with copper dendrites of sub-micrometers or nanometers. The filled AP recrystallized around copper dendrites. In this way, AP had a high contact area with FPCu. To investigate the effect of FPCu on the thermal decomposition of AP, DSC-QMS was employed to trace the thermal effects of the composite and examine the gas products. The results showed that the catalyzed reaction occurred in Tammann temperature region (216-289 degrees C) of AP and the endothermic peak of AP crystal transition disappeared. The amount of the gas products was negligible due to their absorption and oxidation on Cu atoms. Eventually, FPCu was entirely oxidized into cupric oxide by the intermediates and gas products. (C) 2013 Elsevier B.V. All rights reserved.