A multifunctional silicone-phenyl contained aliphatic polyamine, PSPA, was originally synthesized and employed to cure bisphenol A epoxy resin (DGEBA) isothermally, and the curing reactions of DGEBA/PSPA were systematically investigated by DSC measurement at 55, 60,65 and 70 degrees C. The model fitting kinetic analysis confirmed that the reaction rate could be simulated with an autocatalytic Kamal model from start to initiation of diffusion control stage. Taking the diffusion effects into account, the extended Kamal model was applied to fit the experimental reaction rate, and acquired good agreement results. The multi-frequency dynamic mechanical analysis shows that the cured DGEBA/PSPA appears at a beta relaxation in low temperature and at an alpha relaxation in higher temperature interval (>80 degrees C). The relaxation activation energies for the alpha and beta relaxations are 80.51 and 832 kJ/mol, separately. (C) 2014 Elsevier B.V. All rights reserved.