Thin Solid Films, Vol.529, 50-53, 2013
Effect of oxygen to argon flow ratio on the properties of Al-doped ZnO films for amorphous silicon thin film solar cell applications
Transparent conductive oxide thin films in solar cell fabrication have attracted much attention due to their high conductivity and transmittance. In this paper, we have investigated the aluminum-doped zinc oxide (AZO) thin films prepared by radiofrequency magnetron sputtering on Asahi U-type SnO2 glass with different O-2/Ar flow ratios in vacuum chamber. Furthermore, the micro-structural, electrical, and optical properties of AZO/SnO2 films were studied. The change in O-2/Ar flow ratios is found to significantly affect the haze value, and slightly affect electrical resistivity and transmittance of the films. Afterward, the fabricated AZO thin films with different O-2/Ar flow ratios were used for building the solar cell devices. The current-voltage and external quantum efficiency characteristics were investigated for the solar cell devices. The optimized O-2/Ar flow ratio of 3 for solar device shows the best efficiency of 10.41%, and a 20% increase in short-circuit current density compared to typical Asahi solar cells. (C) 2012 Elsevier B.V. All rights reserved.
Keywords:Transparent conductive oxide;Aluminum-doped zinc oxide;Radiofrequency magnetron sputtering;Solar cell