This study investigates the electrodeposition process of quaternary copper-zinc-tin-sulfur (CZTS) thin films with a focus on the ability of ligands to bring deposition potentials of the individual elements closer to each other. Our results show that thiocyanate ions (CNS-) can be used as a suitable complexant for the electrodeposition of Cu2ZnSnS4 from aqueous solutions. A complex electrolyte was developed and the composition measurements showed a large potential interval for the deposition of the CZTS thin film material with an appropriate metal ratio. The layers recrystallized in stoichiometric kesterite structure after annealing at 550 degrees C in H2S atmosphere for 60 min. (C) 2013 Elsevier B.V. All rights reserved.