화학공학소재연구정보센터
Thin Solid Films, Vol.544, 296-300, 2013
Facile preparation of continuous indium metal-organic framework thin films on indium tin oxide glass
Continuous indium metal-organic framework thin films of In12O(OH)(12)[(OH)(4)center dot(H2O)(5))][BTC](6) (MIL-96(In)) (BTC = 1,3,5-benzenetricarboxylate) were prepared on indium tin oxide glass by in situ solvothermal growth method. The structure of the films was confirmed by X-ray diffraction. The growth process and the possible growth mechanism of MIL-96(In) films were investigated by a scanning electron microscopy. Furthermore, the influence of the reaction conditions on the morphology and thickness of films was studied. The best crack-free, continuous film with thickness of approximate 6 mu m was obtained at the proper concentrations of InCl3 and H3BTC of 25.0 mmol.l(1) at 100 degrees C for 12 h. (C) 2013 Elsevier B. V. All rights reserved.