화학공학소재연구정보센터
홈 로그인 로그아웃 연락처 사이트맵
Korean Journal of Chemical Engineering, Vol.31, No.12, 2192-2197, December, 2014
DOI10.1007/s11814-014-0152-x  Export Citation
Adsorption of methyl orange using self-assembled porous microspheres of poly(o-chloroaniline)
Muhammad Naveed Anjum1, 2, Khalid Mahmood Zia1, Lihua Zhu2, Haroon-ur-Rashid2, 3, Mirza Nadeem Ahmad1, Mohammad Zuber1, †, and Heqing Tang4
  • 1Institute of Chemistry, Government College University, Faisalabad 38030, Pakistan
  • 2College of Chemistry and Chemical Engineering, Huazhong University of Science and Technology, Wuhan 430074, P. R. China
  • 3Institute of Chemical Sciences, University of Peshawar, Peshawar, Pakistan
  • 4Key Laboratory of Catalysis and Materials Science of the State Ethnic Affairs Commission and Ministry of Education, College of Chemistry and Materials Science, South-Central University for Nationalities, Wuhan 430074, China
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Self-assembled hollow microspheres poly(o-chloroaniline) (POC) have been synthesized by simple oxidative polymerization of o-chloroaniline using camphor-sulfonic acid (CSA) as dopant acid and ammonium persulfate (APS) as oxidant. The POC microspheres were characterized by means of FTIR, XRD and SEM analysis. Adsorption characteristics of POC spheres were studied by using methyl orange (MO) as adsorbate. It was found that adsorption of MO by POC was better described by pseudo-second-order kinetics than any other kinetic model, such as the pseudofirst-order and intra-particle diffusion models. Langmuir adsorption isotherm model was the best to fit experimental data. The results showed that hollow microspheres of POC can be used as novel and low-cost adsorbent for removal of organic dye from waste water.
Keywords:Adsorption;Methyl Orange;Hollow Microspheres;Poly(o-chloroaniline)
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