Preparation of high modulus thin films based on photocurable azido-functionalized ladder-like structured polysilsesquioxanes

Albert Sung Soo Lee; Seung-Sock Choi; So-Hyun Jang; Seung Sang Hwang; Kyung-Youl Baek

Macromolecular Research, Vol.22, No.10, 1109-1114, October, 2014

DOI10.1007/s13233-014-2152-4 Export Citation

Preparation of high modulus thin films based on photocurable azido-functionalized ladder-like structured polysilsesquioxanes

Albert Sung Soo Lee, Seung-Sock Choi, So-Hyun Jang, Seung Sang Hwang , and Kyung-Youl Baek^†

Korea Institute of Science and Technology, Center for Materials Architecturing, Seoul, 136-791, Korea

E-mail:

A series of azido-functionalized ladder-like structures was prepared by direct azidation of ladder-like structured poly(p-chloromethylphenyl)silsesquioxane (LPCMPSQ) and poly(chloropropyl)silsesquioxane (LPAPSQ) in excellent yields with perfect substitution of the chloro-compounds. The azido-functionalized silsesquioxanes obtained were then photocured without additional photoinitiator to give highly cross-linked thin films with an exceptionally high modulus (> 12 GPa). Furthermore, these materials were shown to be patterned through photolithography to give impeccable micropatterned microstructures.

Keywords:polysilsesquioxane;ladder-like structure;photocurable polymers;hybrids

[References]

Li C, Wilkes GL, Chem. Mater., 13, 3663 (2001)
Schottner G, Chem. Mater., 13, 3422 (2001)
Hayashida N, Hirata H, Kamaki T, Usami M, Ushida T, Itoh H, Yoneyama K, Utsunomiya H, Jpn. Appl. Phys., 42, 750 (2003)
Al Akhrass S, Gal F, Damiron D, Alcouffe P, Hawker CJ, Cousin F, Carrot G, Drockenmuller E, Soft Matter, 5, 586 (2009)
Bang J, Bae J, Lowenhielm P, Spiessberger C, Given-Beck SA, Russell TP, Hawker CJ, Adv. Mater., 19(24), 4552 (2007)
Sepeur S, Kunze N, Werner B, Schmidt H, Thin Solid Films, 351(1-2), 216 (1999)
Lee BK, Cha NG, Hong LY, Kim DP, Tanaka H, Lee HY, Kawai T, Langmuir, 26(18), 14915 (2010)
Choi DG, Jeong JH, Sim YS, Lee ES, Kim WS, Bae BS, Langmuir, 21(21), 9390 (2005)
Yang SC, Jin JH, Kwak SY, Bae BS, Macromol. Res., 19(11), 1166 (2011)
Nishino G, Sugimoto H, Nakanishi E, J. Appl. Polym. Sci., 123(1), 307 (2012)
Zhang WA, Muller AHE, Macromolecules, 43(7), 3148 (2010)
Ge ZS, Wang D, Zhou YM, Liu HW, Liu SY, Macromolecules, 42(8), 2903 (2009)
Trastoy B, Perez-Ojeda ME, Sastre R, Chiara JL, Chem. Eur. J., 16, 3883 (2010)
Morita H, J. Photopolym. Sci. Technol., 4, 225 (1991)
Mehenni H, Bakr OM, React. Funct. Polym., 71(11), 1110 (2011)
Nam CY, Qin Y, Park YS, Hlaing H, Lu XH, Ocko BM, Black CT, Grubbs RB, Macromolecules, 45(5), 2338 (2012)
Lee JS, Hong SI, Eur. Polym. J., 38, 387 (2002)
Yasuda N, Yamamoto S, Wada Y, Yanagida S, J. Polym. Sci. A: Polym. Chem., 39(24), 4196 (2001)
Chan CM, Cao GZ, Hong H, Sarikaya M, Robinson T, Nelson L, J. Mater. Res., 15, 148 (2000)
Choi SS, Lee AS, Lee HS, Jeon HY, Baek KY, Choi DH, Hwang SS, J. Polym. Sci. A: Polym. Chem., 49(23), 5012 (2011)
Choi SS, Lee HS, Hwang SS, Choi DH, Baek KY, J. Mater. Chem., 20, 9852 (2010)
Lee ASS, Choi SS, Lee HS, Jeon HY, Baek KY, Hwang SS, J. Polym. Sci. A: Polym. Chem., 50(21), 4563 (2012)
Choi SS, Lee AS, Lee HS, Baek KY, Choi DH, Hwang SS, Macromol. Res., 19, 261 (2010)
Unno M, Matsumoto T, Matsumoto H, J. Organomet. Chem., 692, 307 (2007)

[Referenced By]

[Related Articles]

[1] Li C, Wilkes GL, Chem. Mater., 13, 3663 (2001)

[2] Schottner G, Chem. Mater., 13, 3422 (2001)

[3] Hayashida N, Hirata H, Kamaki T, Usami M, Ushida T, Itoh H, Yoneyama K, Utsunomiya H, Jpn. Appl. Phys., 42, 750 (2003)

[4] Al Akhrass S, Gal F, Damiron D, Alcouffe P, Hawker CJ, Cousin F, Carrot G, Drockenmuller E, Soft Matter, 5, 586 (2009)

[5] Bang J, Bae J, Lowenhielm P, Spiessberger C, Given-Beck SA, Russell TP, Hawker CJ, Adv. Mater., 19(24), 4552 (2007)

[6] Sepeur S, Kunze N, Werner B, Schmidt H, Thin Solid Films, 351(1-2), 216 (1999)

[7] Lee BK, Cha NG, Hong LY, Kim DP, Tanaka H, Lee HY, Kawai T, Langmuir, 26(18), 14915 (2010)

[8] Choi DG, Jeong JH, Sim YS, Lee ES, Kim WS, Bae BS, Langmuir, 21(21), 9390 (2005)

[9] Yang SC, Jin JH, Kwak SY, Bae BS, Macromol. Res., 19(11), 1166 (2011)

[10] Nishino G, Sugimoto H, Nakanishi E, J. Appl. Polym. Sci., 123(1), 307 (2012)

[11] Zhang WA, Muller AHE, Macromolecules, 43(7), 3148 (2010)

[12] Ge ZS, Wang D, Zhou YM, Liu HW, Liu SY, Macromolecules, 42(8), 2903 (2009)

[13] Trastoy B, Perez-Ojeda ME, Sastre R, Chiara JL, Chem. Eur. J., 16, 3883 (2010)

[14] Morita H, J. Photopolym. Sci. Technol., 4, 225 (1991)

[15] Mehenni H, Bakr OM, React. Funct. Polym., 71(11), 1110 (2011)

[16] Nam CY, Qin Y, Park YS, Hlaing H, Lu XH, Ocko BM, Black CT, Grubbs RB, Macromolecules, 45(5), 2338 (2012)

[17] Lee JS, Hong SI, Eur. Polym. J., 38, 387 (2002)

[18] Yasuda N, Yamamoto S, Wada Y, Yanagida S, J. Polym. Sci. A: Polym. Chem., 39(24), 4196 (2001)

[19] Chan CM, Cao GZ, Hong H, Sarikaya M, Robinson T, Nelson L, J. Mater. Res., 15, 148 (2000)

[20] Choi SS, Lee AS, Lee HS, Jeon HY, Baek KY, Choi DH, Hwang SS, J. Polym. Sci. A: Polym. Chem., 49(23), 5012 (2011)

[21] Choi SS, Lee HS, Hwang SS, Choi DH, Baek KY, J. Mater. Chem., 20, 9852 (2010)

[22] Lee ASS, Choi SS, Lee HS, Jeon HY, Baek KY, Hwang SS, J. Polym. Sci. A: Polym. Chem., 50(21), 4563 (2012)

[23] Choi SS, Lee AS, Lee HS, Baek KY, Choi DH, Hwang SS, Macromol. Res., 19, 261 (2010)

[24] Unno M, Matsumoto T, Matsumoto H, J. Organomet. Chem., 692, 307 (2007)