Incorporation of graphene oxide to pH-responsive hydrogel for rapid adsorption-desorption of nanoparticles on patterned hydrogel surface

Ji Ho Jang; Jin Kyung Kim; Do Sung Huh

Macromolecular Research, Vol.22, No.10, 1132-1135, October, 2014

DOI10.1007/s13233-014-2144-4 Export Citation

Incorporation of graphene oxide to pH-responsive hydrogel for rapid adsorption-desorption of nanoparticles on patterned hydrogel surface

Ji Ho Jang, Jin Kyung Kim, and Do Sung Huh^†

Department of Chemistry and Nanoscience and Engineering, Institute of Basic Science, Inje University, Gyeongnam, 621-749, Korea

E-mail:

A new composite pH-responsive hydrogel that is highly sensitive to the adsorption-desorption of nanoparticles by incorporating GO into polymethacrylic acid (PMAA) hydrogel grafted with poly-(ethylne glycol) (PEG) was synthesized. The hydrogel was fabricated to a patterned surface film for rapid response in the adsorption and desorption to pH stimuli. The morphological structure of the patterned hydrogel surface and the adsorption-desorption of Ag nanoparticles to the hydrogel depending on pH change were greatly increased by the incorporation of GO.

[References]

Ding Z, Chen G, Hoffman AS, J. Biomed. Mater. Res., 9, 498 (1998)
Stayton PS, Shimoboji T, Long C, Chilkoti A, Chen GH, Harris JM, Hoffman AS, Nature, 378(6556), 472 (1995)
Hrouz J, Ilavsky M, Ulbrich K, Kopecek J, J. Eur. Polym., 17, 361 (1981)
Kwon IC, Bae YH, Kim SW, Nature, 354, 291 (1991)
Suzuki A, Tanaka T, Nature, 346, 345 (1990)
Qiu Y, Park K, Adv. Drug Deliv. Rev., 53, 321 (2001)
Peppas NA, Leobandung W, Sci. Polym. Ed., 15, 125 (2004)
Tanaka T, Fillmore DJ, J. Chem. Phys., 70, 1214 (1979)
Kuckling D, Vo CD, Wohlrab SE, Langmuir, 18(11), 4263 (2002)
Beines PW, Klosterkamp I, Menges B, Jonas U, Knoll W, Langmuir, 23(4), 2231 (2007)
Kim H, Abdala AA, Macosko CW, Macromolecules, 43(16), 6515 (2010)
Sun S, Wu P, J. Mater. Chem., 21, 4095 (2011)
Lee C, Wei XD, Kysar JW, Hone J, Science, 321, 385 (2008)
Hummers WS, Offeman RE, J. Am. Chem. Soc., 80, 1339 (1958)
Sun X, Liu Z, Welsher K, Robinson J, Goodwin A, Zaric S, Dai H, Nano Res., 1, 203 (2008)
Pitois O, Francois B, Colloid Polym. Sci., 277, 574 (1999)
Chen Y, Zhuang Q, Liu X, Liu J, Lin S, Han Z, Nanotechnology, 24, 245702 (2013)
Ashok Kumar NA, Choi HJ, Shin YR, Chang DW, Dai L, Baek JB, Acs Nano, 6(2), 1715 (2012)
Kim JK, Kim KI, Basavaraja C, Rabai G, Huh DS, J. Phys. Chem. B, 117(20), 6294 (2013)
Sileikaite A, Prosycevas I, Puiso J, Juraitis A, Guobiene A, Mater. Sci., 12, 287 (2006)

[Referenced By]

[1] Ding Z, Chen G, Hoffman AS, J. Biomed. Mater. Res., 9, 498 (1998)

[2] Stayton PS, Shimoboji T, Long C, Chilkoti A, Chen GH, Harris JM, Hoffman AS, Nature, 378(6556), 472 (1995)

[3] Hrouz J, Ilavsky M, Ulbrich K, Kopecek J, J. Eur. Polym., 17, 361 (1981)

[4] Kwon IC, Bae YH, Kim SW, Nature, 354, 291 (1991)

[5] Suzuki A, Tanaka T, Nature, 346, 345 (1990)

[6] Qiu Y, Park K, Adv. Drug Deliv. Rev., 53, 321 (2001)

[7] Peppas NA, Leobandung W, Sci. Polym. Ed., 15, 125 (2004)

[8] Tanaka T, Fillmore DJ, J. Chem. Phys., 70, 1214 (1979)

[9] Kuckling D, Vo CD, Wohlrab SE, Langmuir, 18(11), 4263 (2002)

[10] Beines PW, Klosterkamp I, Menges B, Jonas U, Knoll W, Langmuir, 23(4), 2231 (2007)

[11] Kim H, Abdala AA, Macosko CW, Macromolecules, 43(16), 6515 (2010)

[12] Sun S, Wu P, J. Mater. Chem., 21, 4095 (2011)

[13] Lee C, Wei XD, Kysar JW, Hone J, Science, 321, 385 (2008)

[14] Hummers WS, Offeman RE, J. Am. Chem. Soc., 80, 1339 (1958)

[15] Sun X, Liu Z, Welsher K, Robinson J, Goodwin A, Zaric S, Dai H, Nano Res., 1, 203 (2008)

[16] Pitois O, Francois B, Colloid Polym. Sci., 277, 574 (1999)

[17] Chen Y, Zhuang Q, Liu X, Liu J, Lin S, Han Z, Nanotechnology, 24, 245702 (2013)

[18] Ashok Kumar NA, Choi HJ, Shin YR, Chang DW, Dai L, Baek JB, Acs Nano, 6(2), 1715 (2012)

[19] Kim JK, Kim KI, Basavaraja C, Rabai G, Huh DS, J. Phys. Chem. B, 117(20), 6294 (2013)

[20] Sileikaite A, Prosycevas I, Puiso J, Juraitis A, Guobiene A, Mater. Sci., 12, 287 (2006)