화학공학소재연구정보센터
홈 로그인 로그아웃 연락처 사이트맵
Journal of Industrial and Engineering Chemistry, Vol.20, No.6, 4066-4075, November, 2014
DOI10.1016/j.jiec.2013.12.108  Export Citation
Controllable synthesis of Bi2S3 via a simple hydrothermal approach starting from an inorganic precursor
Masoud Salavati-Niasari1, 2, †, Zeynab Behfard2, and Mahnaz Maddahfar2
  • 1Institute of Nano Science and Nano Technology, University of Kashan, Kashan, 87317-51167, Iran
  • 2Department of Inorganic Chemistry, Faculty of Chemistry, University of Kashan, Kashan, 87317-51167, Iran
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A hydrothermal method was used to fabricate Bi2S3 with different morphologies (nanoparticles, nanoflaked flowers and nanothorny columniform structures) using bismuth(III) monosalicylate [BiO(C7H5O3)] and three kinds of sulfur sources [L-cysteine, thiourea and thioacetamide in water, respectively]. The influences of the reaction conditions are discussed and possible mechanism for the formation of different Bi2S3 nanostructures is proposed. The products were characterized by XRD, UV-vis, PL, FT-IR. Bismuth salicylate, which is known to be a complex, may play a critical role as a precursor and a template for the growth of linear bismuth sulfide nanorods.
Keywords:Nanorod;L-Cysteine;Semiconductors;Bismuth sulfide;Hydrothermal method
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