Sonochemical synthesis of CoFe2O4 nanoparticles and their application in magnetic polystyrene nanocomposites

Jilla Saffari; Davood Ghanbari; Noshin Mir; Khatereh Khandan-Barani

Journal of Industrial and Engineering Chemistry, Vol.20, No.6, 4119-4123, November, 2014

DOI10.1016/j.jiec.2014.01.010 Export Citation

Sonochemical synthesis of CoFe2O4 nanoparticles and their application in magnetic polystyrene nanocomposites

Jilla Saffari^†, Davood Ghanbari¹, Noshin Mir², and Khatereh Khandan-Barani

Department of Chemistry, Islamic Azad University, Zahedan Branch, P.O. Box 98135-978, Zahedan, Iran
¹Young Researchers and Elite Club, Arak Branch, Islamic Azad University, Arak, Iran
²Department of Chemistry, University of Zabol, P.O. Box 98615-538, Zabol, Iran

E-mail:

CoFe2O4 (CoFe) nanoparticles were synthesized via a facile surfactant-free sonochemical reaction. For preparation of magnetic polymeric films, CoFe2O4 nanoparticles were added to polystyrene (PS). Nanoparticles were characterized using X-ray diffraction (XRD), scanning electron microscopy (SEM), and transmission electron microscopy (TEM). Magnetic properties of the samples were investigated using an alternating gradient force magnetometer (AGFM). CoFe2O4 nanoparticles exhibit a ferromagnetic behaviour with a saturation magnetization of 62 emu/g and a coercivity of 640 Oe at room temperature. By preparing magnetic films the coercivity is increased. The coercivity of PS/CoFe2O4 (10%) nanocomposites is higher than that obtained for PS/CoFe2O4 (30%).

Keywords:PS;CoFe2O4;Sonochemical method;Nanocomposite

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[2] Pankhurst QA, Connolly J, Jones SK, Dobson J, J. Phys. D-Appl. Phys., 36, R167 (2003)

[3] Sun C, Lee JSH, Zhang M, Adv. Drug Deliv. Rev., 60, 1252 (2008)

[4] Kim YH, Park SJ, Curr. Appl. Phys., 11(3), 462 (2011)

[5] Geng BY, Ma JZ, You JH, Cryst. Growth Des., 8, 1443 (2008)

[6] Jia B, Gao L, J. Phys. Chem. C, 112, 666 (2008)

[7] Sun X, Zheng C, Zhang F, Yang Y, Wu G, Yu A, Guan N, J. Phys. Chem. C, 113, 16002 (2009)

[8] Jalajerdi R, Gholamian F, Shafie H, Moraveji A, Ghanbari D, J. Nanostructures, 2, 105 (2012)

[9] Nabiyouni G, Ghanbari D, J. Appl. Polym. Sci., 125(4), 3268 (2012)

[10] Sankaranarayanan VK, Pankhurst QA, Dickson DPE, Johnson CE, J. Magn. Magn. Mater., 120, 73 (1993)

[11] Shafi KVPM, Felner I, Mastai Y, Gedanken A, J. Phys. Chem. B, 103(17), 3358 (1999)

[12] Sabet M, Salavati-Niasari M, Ashjari M, Ghanbari D, Dadkhah M, J. Inorg. Organomet. Polym., 22, 1139 (2012)

[13] Sabet M, Salavati-Niasari M, Ghanbari D, Amiri O, Yousefi M, Mater. Sci. Semicond. Process, 16, 696 (2013)

[14] Salavati-Niasari M, Esmaeili E, Sabet M, J. Cluster Sci., 24, 799 (2013)

[15] Matuevic E, J. Colloid Interface Sci., 117, 593 (1987)

[16] Nabiyouni G, Ghanbari D, Yousofnejad A, Seraj M, J. Ind. Eng. Chem., http://dx.doi.org/10.1016/j.jiec.2013.12.030 (2014)

[17] Kucuk B, Ozkan N, Volkan M, Mater. Lett., 98, 90 (2013)

[18] Nabiyouni G, Yousofnejad A, Seraj M, Akhtarian F, Ghanbari D, J. Nanostructures, 2, 525 (2013)

[19] Yang Z, Wang CS, Li XH, Zeng HX, Mater. Sci. Eng. B-Solid State Mater. Adv. Technol., 90, 142 (2002)

[20] Ghanbari D, Salavati-Niasari M, Sabet M, J. Cluster Sci., 23, 1081 (2012)

[21] Lisjak D, Drofenik M, J. Eur. Ceram. Soc., 26, 3681 (2006)

[22] Topal U, Ozkan H, Sozeri H, J. Magn. Magn. Mater., 284, 416 (2004)