화학공학소재연구정보센터
홈 로그인 로그아웃 연락처 사이트맵
Journal of Industrial and Engineering Chemistry, Vol.20, No.6, 4473-4481, November, 2014
DOI10.1016/j.jiec.2014.02.019  Export Citation
One step green synthesis of hexagonal silver nanoparticles and their biological activity
Samy M. Shaban†, Ismail Aiad, Mohamed M. El-Sukkary, E.A. Soliman1, and Moshira Y. El-Awady
  • Petrochemical Department, Egyptian Petroleum Research Institute, Egypt, Korea
  • 1Faculty of Science, Ain Shams University, Cairo, Egypt
E-mail:
Hexagonal and spherical silver nanoparticles were prepared by in situ and green synthesis using sun light as reducing agent with assistance newly prepared cationic surfactant which act also as capping agents. The silver nanoparticles formation was investigated using UV-vis spectrophotometer, transmission electron microscope (TEM), dynamic light scattering (DLS), energy dispersive X-ray (EDX) and FTIR. The results showed formation uniform, well arrangement hexagonal and spherical shapes. Increasing hydrophobic chain length increase the stability and amount of AgNPS. Both prepared surfactants and surfactants capping silver nanoparticles showed high antimicrobial activity against Gram-positive and Gram-negative bacteria.
Keywords:Photosynthesis;Hexaonal shapes;Zetapotential;Biological activity
  1. Solomon SD, Bahadory M, Jeyarajasingam AV, Rutkowsky SA, Boritz C, Mulfinger L, J. Chem. Educ., 84, 322 (2007)
  2. Rodriguez-Sanchez L, Blanco MC, Lopez-Quintela MA, J. Phys. Chem. B, 104(41), 9683 (2000)
  3. Huang HH, Ni XP, Loy GL, Chew CH, Tan KL, Loh FC, Deng JF, Xu GQ, Langmuir, 12(4), 909 (1996)
  4. Tsuji M, Nishizawa Y, Matsumoto K, Miyamae N, Tsuji T, Zhang X, Colloids Surf. A: Physicochem. Eng. Asp., 293, 185 (2007)
  5. Cai MM, Chen JL, Zhou J, Appl. Surf. Sci., 226(4), 422 (2004)
  6. Taleb A, Petti C, Pileni MP, Chem. Mater., 9, 950 (1997)
  7. Cheng DM, Zhou XD, Xia HB, Chan HSO, Chem. Mater., 17, 3578 (2005)
  8. Poliakoff M, Anastas P, Nature, 413, 257 (2001)
  9. Raveendran P, Fu J, Wallen SL, J. Green Chem., 8, 34 (2006)
  10. Aymonier C, Schlotterbeck U, Antonietti L, Zacharias P, Thomann R, Tiller JC, Mecking S, Chem. Commun., 24, 3018 (2002)
  11. Shiraishi Y, Toshima N, Colloids Surf. A: Physicochem. Eng. Asp., 169, 59 (2000)
  12. Sato T, Ahemd H, Brown D, Johnson BFG, J. Appl. Phys., 82, 696 (1997)
  13. Wuelfing WP, Zamborini FP, Templeton AC, Ween XG, Yoon H, Murray RW, Chem. Mater., 13, 87 (2001)
  14. Frederix F, Friedt JM, Choi KH, Laureyn W, Campetelli A, Mondelears D, Maes G, Borghs G, Anal. Chem., 75, 6894 (2003)
  15. Bakker E, Anal. Chem., 76, 3285 (2004)
  16. Sondi I, Salopek-Sondi B, J. Colloid Interface Sci., 275(1), 177 (2004)
  17. Aiad I, El-Sukkary MM, Soliman EA, El-Awady MY, Shaban SM, J. Ind. Eng. Chem., http://dx.doi.org/10.1016/j.jiec.2013.08.010 (2013)
  18. Aiad I, El-Sukkary MM, Soliman EA, El-Awady MY, Shaban SM, J. Ind. Eng. Chem., 10.1016/j.jiec.2013.12.031 (2014)
  19. Muanza DN, Kim BW, Euler KL, Williams L, Int. J. Pharmacogn., 32, 337 (1994)
  20. Yang Y, Shi JL, Tanaka T, Nogami M, Langmuir, 23(24), 12042 (2007)
  21. Goia DV, J. Mater. Chem., 14, 451 (2004)
  22. El-Rafie MH, El-Naggar ME, Ramadan MA, Fouda MMG, Al-Deyab SS, Hebeish A, Carbohydr. Polym., 86, 630 (2011)
  23. Spinks JWT, Woods RJ, Year, Water and Inorganic Aqueous Systems: An introduction to Radiation Chemistry, 3rd ed., Wiley Interscience, New York, 1990p. 255.
  24. Henglein A, Chem. Mater., 10, 444 (1998)
  25. Belloni J, Mostafavi M, Remita H, Marignier JL, Delcourt MO, New J. Chem., 22, 1239 (1998)
  26. Guzman MG, Dille J, Godet S, World Acad. Sci. Eng. Technol., 43, 357 (2008)
  27. Chun-Hua W, Li-Ren L, Ai-Min Y, Yu Z, De-An L, Zhi-Juan H, Chin. Phys., 16, 100 (2007)
  28. Courrol LC, Silva FRDO, Gomes L, Colloids Surf. A: Physicochem. Eng. Asp., 305, 54 (2007)
  29. Kelly KL, Coronado E, Zhao LL, Schatz GC, J. Phys. Chem. B, 107(3), 668 (2003)
  30. Pastoriza-Santos I, Serra-Rodriguez C, Liz-Marzan LM, J. Colloid Interface Sci., 221(2), 236 (2000)
  31. Jradi S, Balan L, Zeng XH, Plain J, Lougnot DJ, Royer P, Nanotechnology, 21, 95605 (2010)
  32. Roldan MV, Scaffardi LB, de Sanctis O, Pellegri N, Mater. Chem. Phys., 112(3), 984 (2008)
  33. Wei G, Wang L, Sun LL, Song YH, Sun YJ, Guo CL, J. Phys. Chem. C, 111, 1976 (2007)
  34. Chen M, Feng YG, Wang X, Li TC, Zhang JY, Qian DJ, Langmuir, 23(10), 5296 (2007)
  35. Zhang Y, Yang M, Portney NG, Cui D, Budak G, Ozbay E, Ozkan M, Ozkan CS, Biomed. Microdevices, 10, 321 (2008)
  36. Ho J, Danquah MK, Wang HT, Forde GM, J. Chem. Technol. Biotechnol., 83(3), 351 (2008)
  37. Hedberg J, Lundin M, Lowe T, Blomberg E, Wold S, Wallinder IO, J. Colloid Interface Sci., 369, 193 (2012)
  38. Magudapatty G, Gangopaghyayrans P, Panigrahi BK, Nair KGM, Dhara S, Phys. Rev., B, Condens. Matter, 299, 142 (2001)
  39. Newman JDS, Blanchard GJ, Langmuir, 22(13), 5882 (2006)
  40. Balgavy P, Devinsky F, Adv. Colloid Interface Sci., 66, 23 (1996)
  41. Nagamune H, Maeda T, Ohkura K, Yamamoto K, Nakajima M, Kourai H, Toxicol. Vitro, 14, 139 (2000)
  42. Birnie CR, Malamud D, Schnaare RL, Antimicrob. Agents Chemother., 44, 2514 (2000)
  43. Pernak J, Kalewska J, Ksycinska H, Cybulski J, Eur. J. Med. Chem., 36, 899 (2001)
  44. Viscardi G, Quagliotto P, Barolo C, Savarino P, Barni E, Fisciaro E, J. Argo Chem., 65, 8197 (2000)
  45. Campanac C, Pineau L, Payard A, Baziard-Mouysset G, Roques C, Antimicrob. Agents Chemother., 46, 1469 (2002)
  46. Janoff A, Pringle M, Miller K, Biochim. Biophys. Acta, 649, 125 (1981)
  47. Pringle M, Brown K, Miller K, Mol. Pharmacol., 19, 49 (1981)