화학공학소재연구정보센터
Macromolecular Research, Vol.22, No.11, 1238-1241, November, 2014
Compression behavior of a pressure-sensitive adhesive material
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The isotherms of compression strains for poly(2-ethylhexyl acrylate) (PEHA) at seleted temperatures are superposed into a single characteristic curve as a function of dimensionless (P-Po)/Bo, which is the basis of Temperature-Pressure superposition in compression behavior of PEHA. The superposed curve is signified by the temperature insensive pressure coefficient B1 of the bulk modulus for the polymer, where its value is unexpectedly higher than what is known for most of nonpolar organic polymers.
  1. Chalikian TV, Annu. Rev. Biophys. Biomol. Struct., 32, 207 (2003)
  2. Zoller P, Walsh D, Standard Pressure-Volume-Temperature Data for Polymers, Technomic Publishing Co., Inc., Lancaster (1995)
  3. Flory PJ, Orwoll RA, Vrij A, J. Am. Chem. Soc., 86, 3515 (1964)
  4. Sanchez IC, Lacombe RH, J. Phys. Chem., 80, 2352 (1976)
  5. Sanchez IC, Lacombe RH, Macromolecules, 11, 1145 (1978)
  6. Dee GT, Walsh DJ, Macromolecules, 21, 811 (1988)
  7. Nemirovsky AM, Bawendi MG, Freed KF, J. Chem. Phys., 87, 7272 (1987)
  8. Dudowicz J, Freed KF, Macromolecules, 24, 5076 (1991)
  9. Rodgers PA, J. Appl. Polym. Sci., 48, 1061 (1993)
  10. Cho J, Sanchez IC, in Polymer Handbook, Brandrup J, Immergut EH, Grulke EA, Eds., Wiley Interscience, New York, p VI/591. (1999)
  11. Sanchez IC, Cho J, Chen WJ, Macromolecules, 26, 4234 (1993)
  12. Sanchez IC, Cho J, Polymer, 36(15), 2929 (1995)
  13. Cho J, Sanchez IC, Macromolecules, 31(19), 6650 (1998)
  14. Cho JH, Macromolecules, 33(6), 2228 (2000)
  15. Sanchez IC, Cho J, Chen WJ, J. Phys. Chem., 97, 6120 (1993)
  16. Creton C, MRS Bull., 434 (2003)
  17. Cantor AS, Wirtanen DJ, Pharm. Technol., 26, 28 (2002)
  18. Ozawa T, Ishiwata S, Kano Y, Furukawa Rev., 83 (2001)
  19. Don TM, Huang ML, Chiu AC, Kuo KH, Chiu WY, Chiu LH, Mater. Chem. Phys., 107(2-3), 266 (2008)