플렉서블 Li/MnO2 일차전지의 제조공정에 따른 전기적 특성

이미재; 채유진; 김진호; 황종희; 박상선; Mi-Jai Lee; Yoo-Jin Chae; Jin-Ho Kim; Jong-Hee Hwang; Sang-Sun Park

Korean Journal of Materials Research, Vol.22, No.12, 717-721, December, 2012

DOI10.3740/MRSK.2012.22.12.717 Export Citation

플렉서블 Li/MnO2 일차전지의 제조공정에 따른 전기적 특성

Electrical Characteristics According to the Manufacturing Process of the Flexible Li/MnO2 Primary Cell

이미재^†, 채유진, 김진호 , 황종희 , 박상선¹

한국세라믹기술원
¹(주)비츠로셀

Mi-Jai Lee^†, Yoo-Jin Chae, Jin-Ho Kim , Jong-Hee Hwang , and Sang-Sun Park¹

Korea Institute of Ceramic Engineering & Technology, Korea
¹Vitzrocell, Korea

E-mail:

Manganese dioxide (MnO2) is one of the most important cathode materials used in both aqueous and non-aqueous batteries. The MnO2 polymorph that is used for lithium primary batteries is synthesized either by electrolytic (EMD-MnO2) or chemical methods (CMD-MnO2). Commonly, electrolytic manganese dioxide (EMD) is used as a cathode mixture material for dry-cell batteries, such as a alkaline batteries, zinc-carbon batteries, rechargeable alkaline batteries, etc. The characteristics of lithium/manganese-dioxide primary cells fabricated with EMD-MnO2 powders as cathode were compared as a function of the parameters of a manufacturing process. The flexible primary cells were prepared with EMD-MnO2, active carbon, and poly vinylidene fluoride (PVDF) binder (10 wt.%) coated on an Al foil substrate. A cathode sheet with micro-porous showed a higher discharge capacity than a cathode sheet compacted by a press process. As the amount of EMD-MnO2 increased, the electrical conductivity decreased and the electrical capacity increased. The cell subjected to heat-treatment at 200 oC for 1 hr showed a high discharge capacity. The flexible primary cell made using the optimum conditions showed a capacity and an average voltage of 220 mAh/g and 2.8 V, respectively, at 437.5 μA.

Keywords:Li/MnO2;flexible primary cell;RFID;active tag;USN

[References]

Dell RM, Solid State Ionics, 143, 139 (2009)
Lee TJ, Cheng TT, Juang HK, Chen SY, Fey GTK, Jaw HK, J. Power Sources, 44, 709 (1993)
Ohzuku T, Kitagawa M, Hirai T, J. Electrochem. Soc., 136, 3169 (1989)
Shaohorn Y, Hackney SA, Cornilsen BC, J. Electrochem. Soc., 144(9), 3147 (1997)
Chabre Y, Pannetier J, Prog. Solid State Chem., 23, 1 (1995)
Andersen TN, Progress in Batteries & Battery Materials, Vol. 11, p. 105-129, eds. D. A. J. Swinkels, Ite-Jec Press, Inc., Ohio, USA. (1992)
Williams R, Fredlein R, Lawrance G, Swinkels D, Ward C, Progress in Batteries & Battery Materials, Vol. 13, p. 102-112, eds. D. A. J. Swinkels, Ite-Jec Press, Inc., Ohio, USA. (1994)
Wolff PMD, Visser JW, Giovanoli R, Brutsch R, Chimia, 32, 257 (1978)
Akashi H, Tanaka K, Sekai K, J. Power Sources, 104(2), 241 (2002)
Lee JA, Newnham CE, Stone FS, Tye FL, J. Colloid Interface Sci., 45, 289 (1973)
Tye FL, Electrochim. Acta, 21, 415 (1976)
Reuschi P, J. Electrochem. Soc., 131, 2737 (1984)
Fillaux F, Cachet CH, Ouboumour H, Tomkinson J, Levy-Clement C, Yu LT, J. Electrochem. Soc., 140, 585 (1993)

[Related Articles]

[1] Dell RM, Solid State Ionics, 143, 139 (2009)

[2] Lee TJ, Cheng TT, Juang HK, Chen SY, Fey GTK, Jaw HK, J. Power Sources, 44, 709 (1993)

[3] Ohzuku T, Kitagawa M, Hirai T, J. Electrochem. Soc., 136, 3169 (1989)

[4] Shaohorn Y, Hackney SA, Cornilsen BC, J. Electrochem. Soc., 144(9), 3147 (1997)

[5] Chabre Y, Pannetier J, Prog. Solid State Chem., 23, 1 (1995)

[6] Andersen TN, Progress in Batteries & Battery Materials, Vol. 11, p. 105-129, eds. D. A. J. Swinkels, Ite-Jec Press, Inc., Ohio, USA. (1992)

[7] Williams R, Fredlein R, Lawrance G, Swinkels D, Ward C, Progress in Batteries & Battery Materials, Vol. 13, p. 102-112, eds. D. A. J. Swinkels, Ite-Jec Press, Inc., Ohio, USA. (1994)

[8] Wolff PMD, Visser JW, Giovanoli R, Brutsch R, Chimia, 32, 257 (1978)

[9] Akashi H, Tanaka K, Sekai K, J. Power Sources, 104(2), 241 (2002)

[10] Lee JA, Newnham CE, Stone FS, Tye FL, J. Colloid Interface Sci., 45, 289 (1973)

[11] Tye FL, Electrochim. Acta, 21, 415 (1976)

[12] Reuschi P, J. Electrochem. Soc., 131, 2737 (1984)

[13] Fillaux F, Cachet CH, Ouboumour H, Tomkinson J, Levy-Clement C, Yu LT, J. Electrochem. Soc., 140, 585 (1993)