Korean Journal of Materials Research, Vol.21, No.4, 212-215, April, 2011
Bebq2에 (pq)2Ir(acac)가 선택 도핑된 2-파장 유기발광다이오드
2-Wavelength Organic Light-Emitting Diodes Using Bebq2 Selectively Doped with (pq)2Ir(acac)
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New organic light-emitting diodes with structure of indium-tin-oxide[ITO]/N,N’-diphenyl-N, N’-bis-[4-(phenyl-mtolvlamino)- phenyl]-biphenyl-4,4’-diamine[DNTPD]/1,1-bis-(di-4-poly-aminophenyl) cyclohexane[TAPC]/bis(10-hydroxy-benzo (h)quinolinato)beryllium[Bebq2]/Bebq2:iridium(III)bis(2-phenylquinoline-N,C2')acetylacetonate[(pq)2Ir(acac)]/ET-137[electron transport material from SFC Co]/LiF/Al using the selective doping of 5%-(pq)2Ir(acac) in a single Bebq2 host in the two wavelength (green, orange) emitter formation were proposed and characterized. In the experiments, with a 300A-thick undoped emitter of Bebq2, two kinds of devices with the doped emitter thicknesses of 20A and 40A in the Bebq2:(pq)2Ir(acac) were fabricated. The device with a 20A-thick doped emitter is referred to as “D-1” and the device with a 40A-thick doped emitter is referred to as “D-2”. Under an applied voltage of 9V, the luminance of D-1 and D-2 were 7780 cd/m2 and 6620 cd/m2, respectively. The electroluminescent spectrum of each fabricated device showed peak emissions at the same two wavelengths: 508 nm and 596 nm. However, the relative intensity of 596 nm to 508 nm at those wavelengths was higher in the D-2 than in the D-1. The D-1 and D-2 devices showed maximum current efficiencies of 5.2 cd/A and 6.0 cd/A, and color coordinates of (0.31, 0.50) and (0.37, 0.48) on the Commission Internationale de I'Eclairage[CIE] chart, respectively.
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