화학공학소재연구정보센터
Korean Journal of Materials Research, Vol.18, No.7, 389-393, July, 2008
나노 Ag spot-coated TiO2-SrO 복합분체의 합성과 광촉매 활성 평가
Synthesis and Photocatalytic Activity of Ag Spot-coated TiO2-SrO Composite Powders
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Nano-sized TiO2-60 wt% SrO composite powders were synthesized by a sol-gel method using titanium isopropoxide and Sr(OH)2 ·8H2O as precursors. 3, -5, -7 wt%Ag spot-coated TiO2-60 wt% SrO composite powders were synthesized by a Ag electroless deposition method using TiO2-60 wt% SrO composite powders calcined at 1050oC, which mainly exhibited the SrTiO3phase. However, a small number of rutile TiO2, Sr2TiO4 and SrO2 phases were also detected. In the Ag spot-coated powders synthesized by electroless deposition, nano-sized particles about 5-25 nm in diameter adhered to the TiO2-60 wt% SrO composite powders. The photocatalytic activity of Ag spot-coated TiO2-SrO and TiO2-SrO composite powders for degradation of phenol showed that all of TiO2-SrO composite powders were highly active under UV light irradiation. 7 wt%Ag spot-coated TiO2-60 wt.%SrO composite powders had a relatively higher photocatalytic activity than did TiO2-SrO composite powders under visible light.
  1. Fujishima A, Rao TN, Tryk DA, J. Photochem. Photobiol. C, 1, 1 (2000)
  2. Ruan SP, Wu FQ, Zhang T, Gao W, Xu BK, Zhao MY, Mater. Chem. Phys., 69(1-3), 7 (2001)
  3. Hirano M, Ota K, Tanike O, Inagaki M, J. Solid State Chem., 170, 39 (2003)
  4. Belver C, Bellod R, Fuerte A, Fernandez-Garcia M, Appl. Catal. B: Environ., 65(3-4), 301 (2006)
  5. Chang CH, Shen YH, Mater. Lett., 60, 129 (2006)
  6. Lee BT, Han JK, Saito F, Mat. Lett., 60, 2101 (2006)
  7. Han JK, Choi SM, Lee GH, Mat. Lett., 61, 3798 (2007)
  8. Das D, Mishra HK, Parida KM, Dalai AK, J. Mol. Catal. A-Chem., 189(2), 271 (2002)
  9. Liu B, Zhao X, Zhang N, Zhao Q, He X, Feng J, Sur. Sci., 595, 203 (2005)
  10. Wang JS, Shu Y, Zhang QW, Saito F, Sato T, Solid State Ion., 172(1-4), 191 (2004)
  11. Ueda M, Otsuka-Yao-Matsuo S, Sci. Tech. Adv. Mat., 5, 187 (2004)
  12. Inagaki M, Nakazawa Y, Hirano M, Kobayashi Y, Toyoda M, Int. J. Inorg., 3, 809 (2001)
  13. Han JK, Choi SM, Hong WS, Lee BT, J. Kor. Inst. Met. & Mater, 45(8), 484 (2007)