비납계 Bi0.5Na0.5의 강유전 및 압전 특성에 미치는 Nb-doping 효과

여홍구; 성연수; 송태권; 조종호; 정순종; 송재성; 김명호; Hong-Goo Yeo; Yeon-Soo Sung; Tae-Kwon Song; Jong-Ho Cho; Soon-Jong Jeong; Jae-Sung Song; Myong-Ho Kim

Korean Journal of Materials Research, Vol.16, No.11, 705-709, November, 2006

DOI10.3740/MRSK.2006.16.11.705 Export Citation

비납계 Bi0.5Na0.5의 강유전 및 압전 특성에 미치는 Nb-doping 효과

Nb-doping Effects on Ferroelectric and Piezoelectric Properties of Pb-free Bi0.5Na0.5

여홍구, 성연수, 송태권, 조종호, 정순종¹, 송재성¹, 김명호^†

창원대학교 나노.신소재 공학부
¹한국전기연구원 전자기소자그룹

Hong-Goo Yeo, Yeon-Soo Sung, Tae-Kwon Song, Jong-Ho Cho, Soon-Jong Jeong¹, Jae-Sung Song¹, and Myong-Ho Kim^†

School of Nano & Advanced Materials Engineering, Changwon National University, Changwon, Gyeongnam 641-120, Korea
¹Korea Electrotechnology Research Institute, Electric and Magnetic Devices Research Group, Changwon, Gyeongnam 641-120, Korea

E-mail:

Nb was doped to Pb-free (BNT) by a solid state mixing process to form (BNTNb) and its doping effects on ferroelectric and piezoelctric properties of BNT were investigated. The BNTNb solid solutions were formed up to x=0.01 with no apparent second phases while grain sizes decreased. As x increased, coercive field () and mechanical quality factor () decreased but piezoelectric constant () increased, which indicates Nb acts as a donor for BNT.

Keywords:bismuth sodium titanate;ferroelectric;P-E hysteresis loop;coercive field

[References]

Jaffe B, Roth RS, Marzullo S, J. Appl. Phys., 25, 809 (1954)
Smolenskii GA, Isupov VA, Agranovskaya AI, Kranik NN, Sov. Phys. Solid State, 2(11), 2651 (1961)
Sasaki A, Chiba T, Mamiya Y, Otsuki E, Jpn. J. Appl. Phys., 38, 5564 (1999)
Takenaka T, Maruyama K, Sakata K, Jpn. J. Appl. Phys., 30(9B), 2236 (1991)
Takenaka T, Okuda T, Takegahara K, Ferroclcctrics, 196, 175 (1997)
Li Y, Chen W, Zhou J, Xu Q, Sun H, Xu R, Mater. Sci. Eng. B, 112, 5 (2004)
Nagata H, Takenaka T, Jpn. J. Appl. Phys., 36, 6055 (1997)
Herabut A, Safari A, J. Am. Ceram. Soc., 80(11), 2954 (1997)
Lewis GV, Catlow CRA, J. Am. Ceram. Soc., 68(10), 555 (1985)
Yi JY, Lee JK, Hong KS, J. Am. Ceram. Soc., 85(12), 3004 (2002)
Lucuta PG, Constantinescu F, Barb D, J. Am. Ceram. Soc., 68(10), 533 (1985)
Park SE, Chung SJ, Kim IT, Hong KS, J. Am. Ceram, Soc., 77, 2641 (1994)
Jaffe B, Cook WR, Jr, Jaffe H, Piezoelectric Ceramcis, p154, Academic Press, New York, (1971) (1971)
Huang CL, Chen BH, Solid State Communications, 130, 19 (2004)

[1] Jaffe B, Roth RS, Marzullo S, J. Appl. Phys., 25, 809 (1954)

[2] Smolenskii GA, Isupov VA, Agranovskaya AI, Kranik NN, Sov. Phys. Solid State, 2(11), 2651 (1961)

[3] Sasaki A, Chiba T, Mamiya Y, Otsuki E, Jpn. J. Appl. Phys., 38, 5564 (1999)

[4] Takenaka T, Maruyama K, Sakata K, Jpn. J. Appl. Phys., 30(9B), 2236 (1991)

[5] Takenaka T, Okuda T, Takegahara K, Ferroclcctrics, 196, 175 (1997)

[6] Li Y, Chen W, Zhou J, Xu Q, Sun H, Xu R, Mater. Sci. Eng. B, 112, 5 (2004)

[7] Nagata H, Takenaka T, Jpn. J. Appl. Phys., 36, 6055 (1997)

[8] Herabut A, Safari A, J. Am. Ceram. Soc., 80(11), 2954 (1997)

[9] Lewis GV, Catlow CRA, J. Am. Ceram. Soc., 68(10), 555 (1985)

[10] Yi JY, Lee JK, Hong KS, J. Am. Ceram. Soc., 85(12), 3004 (2002)

[11] Lucuta PG, Constantinescu F, Barb D, J. Am. Ceram. Soc., 68(10), 533 (1985)

[12] Park SE, Chung SJ, Kim IT, Hong KS, J. Am. Ceram, Soc., 77, 2641 (1994)

[13] Jaffe B, Cook WR, Jr, Jaffe H, Piezoelectric Ceramcis, p154, Academic Press, New York, (1971) (1971)

[14] Huang CL, Chen BH, Solid State Communications, 130, 19 (2004)