Separation of biomass using carbon molecular sieves treated with hydrogen peroxide

Seho Cho; Dayoung Lee; Young-Seak Lee

Journal of Industrial and Engineering Chemistry, Vol.21, 278-282, January, 2015

DOI10.1016/j.jiec.2013.12.113 Export Citation

Separation of biomass using carbon molecular sieves treated with hydrogen peroxide

Seho Cho, Dayoung Lee, and Young-Seak Lee^†

Department of Fine Chemical Engineering and Applied Chemistry, Chungnam National University, Daejeon 305-764, Republic of Korea

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The effect of functionalized carbon surface on gas separation is investigated in modified carbon molecular sieves (CMSs) with H2O2 for CO2/CH4 mixed gas. The textural properties of the surface changed slightly, with a greater micropore volume and surface area enhancement. The amount of adsorbed CO2 increased from 2.57 for the raw sample to 2.68 mmol/g for the modified CMSs. The breakthrough times for CO2 were after 7.5 min for modified CMSs and 5 min for R-CMS. These effects were due to the interaction between CO2 and oxide groups on the surfaces of CMSs resulting from the H2O2 treatment.

Keywords:Carbon capture;Adsorption;Surface modification;Hydrogen peroxide;Carbon molecular sieve

[References]

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Peng X, Cao D, Wang W, J. Phys. Chem. C, 112, 13024 (2008)
Cho SH, Bai BC, Yu HR, Lee YS, Appl. Chem. Eng., 22(4), 343 (2011)
Kim TJ, Li BA, Hagg MB, J. Polym. Sci. B: Polym. Phys., 42(23), 4326 (2004)
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Jung M, Jeong E, Jang J, Lee Y, Carbon Lett., 11, 28 (2010)
Plaza MG, Pevida C, Arias B, Fermoso J, Casal MD, Martin CF, Rubiera F, Pis JJ, Fuel, 88(12), 2442 (2009)
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Im JS, Kim JG, Lee YS, Carbon, 47, 2640 (2009)
Lee YS, Lee BK, Carbon, 40, 2461 (2002)
Torrisi A, Mellot-Draznieks C, Robert G, J. Chem. Phys., 132, 44705 (2010)
Kim K, Carbon Electrochemical and Physicochemical Properties, Wiley, New York, p. 86. (1988)
Pevida C, Plaza MG, Arias B, Fermoso J, Rubiera F, Pis JJ, Appl. Surf. Sci., 254(22), 7165 (2008)
Lee HM, Kang HR, An KH, Kim HG, Kim BJ, Carbon Lett., 14, 180 (2013)
Thote J, Iyer K, Chatti R, Labhsetwar N, Biniwale R, Rayalu S, Carbon, 48, 396 (2010)
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Zielke U, Huttinger K, Hoffman W, Carbon, 34, 983 (1996)
Bai BC, Cho S, Yu HR, Yi KB, Kim KD, Lee YS, J. Ind. Eng. Chem., 19(3), 776 (2013)
Rashidi NA, Yusup S, Hameed BH, Energy, 61, 440 (2013)
Jung MJ, Jeong E, Kim Y, Lee YS, J. Ind. Eng. Chem., 19(4), 1315 (2013)
Kang DS, Kim BJ, Lee KJ, Kim SH, Lee SW, Roh JS, Carbon Lett., 14, 55 (2013)
Nasr B, Hedi B, Abdellatif G, Rodrigo MA, Chem. Eng. Technol., 28(2), 193 (2005)
Anbia M, Hoseini V, Sheykhi S, J. Ind. Eng. Chem., 18(3), 1149 (2012)
Cui H, Li Q, Gao S, Shang JK, J. Ind. Eng. Chem., 18(4), 1418 (2012)
Bourrelly S, Llewellyn PL, Serre C, Millange F, Loiseau T, Ferey G, J. Am. Chem. Soc., 127(39), 13519 (2005)
Bastin L, Barcia P, Hurtado E, Silva J, Rodrigues A, Chen B, J. Phys. Chem. C, 112, 1575 (2008)

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[9] Lithoxoos GP, Labropoulos A, Peristeras LD, Kanellopoulos N, Samios J, Economou IG, J. Supercrit. Fluids, 55(2), 510 (2010)

[10] Im JS, Kim JG, Lee YS, Carbon, 47, 2640 (2009)

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[12] Torrisi A, Mellot-Draznieks C, Robert G, J. Chem. Phys., 132, 44705 (2010)

[13] Kim K, Carbon Electrochemical and Physicochemical Properties, Wiley, New York, p. 86. (1988)

[14] Pevida C, Plaza MG, Arias B, Fermoso J, Rubiera F, Pis JJ, Appl. Surf. Sci., 254(22), 7165 (2008)

[15] Lee HM, Kang HR, An KH, Kim HG, Kim BJ, Carbon Lett., 14, 180 (2013)

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[17] Tressaud A, Durand E, Labrugere C, J. Fluorine Chem., 125, 1639 (2004)

[18] Jagiello J, Tolles D, in: F. Meunier (Ed.), Fundamentals of Adsorption, 6, Elsevier, Amsterdam, p. 629. (1998)

[19] Kim JG, Im JS, Bae TS, Kim JH, Lee YS, J. Ind. Eng. Chem., 19(1), 94 (2013)

[20] Zielke U, Huttinger K, Hoffman W, Carbon, 34, 983 (1996)

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[22] Rashidi NA, Yusup S, Hameed BH, Energy, 61, 440 (2013)

[23] Jung MJ, Jeong E, Kim Y, Lee YS, J. Ind. Eng. Chem., 19(4), 1315 (2013)

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[25] Nasr B, Hedi B, Abdellatif G, Rodrigo MA, Chem. Eng. Technol., 28(2), 193 (2005)

[26] Anbia M, Hoseini V, Sheykhi S, J. Ind. Eng. Chem., 18(3), 1149 (2012)

[27] Cui H, Li Q, Gao S, Shang JK, J. Ind. Eng. Chem., 18(4), 1418 (2012)

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[29] Bastin L, Barcia P, Hurtado E, Silva J, Rodrigues A, Chen B, J. Phys. Chem. C, 112, 1575 (2008)