Evaluation of the metal-added Mg hydrogen storage material and comparison with the oxide-added Mg

Myoung Youp Song; Hye Ryoung Park; Sung Nam Kwon

Journal of Industrial and Engineering Chemistry, Vol.21, 378-386, January, 2015

DOI10.1016/j.jiec.2014.02.048 Export Citation

Evaluation of the metal-added Mg hydrogen storage material and comparison with the oxide-added Mg

Myoung Youp Song, Hye Ryoung Park¹, and Sung Nam Kwon^†

Division of Advanced Materials Engineering, Research Center of Advanced Materials Development, Engineering Research Institute, Chonbuk National University, 567 Baekje-daero Deokjin-gu, Jeonju, 561-756, South Korea
¹School of Applied Chemical Engineering, Chonnam National University, 77 Yongbong-ro Buk-gu, Gwangju, 500-757, South Korea

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A Mg-5 wt% Ni-2.5 wt% Fe-2.5 wt% Ti (named Mg-5Ni-2.5Fe-2.5Ti) hydrogen storage material was prepared by reactive mechanical grinding, and hydrogen absorption and desorption properties were then investigated by a Sievert’s type volumetric apparatus. The activated Mg-5Ni-2.5Fe-2.5Ti sample absorbed 5.67 wt% H for 60 min at 573K under 12 bar H2 and desorbed 4.72 wt% H for 60 min at 573K under 1.0 bar H2. Mg-5Ni-2.5Fe-2.5Ti had a higher initial hydriding rate at 593K under 12 bar H2 and a higher dehydriding rate at 593K under 1.0 bar H2 than oxide-added Mg samples with Mg-xFe2O3-yNi compositions.

[References]

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Kwak YJ, Park HR, Song MY, Korean J. Met. Mater., 50(11), 855 (2012)
Song MY, Kwon SN, Hong SH, Park HR, Met. Mater. International, 18(2), 279 (2012)
Kwak YJ, Lee SH, Park HR, Song MY, Korean J. Met. Mater., 51(8), 607 (2012)
Song MY, Kwak YJ, Lee SH, Park HR, Korean J. Met. Mater., 51(8), 607 (2012)
Song MY, Kwak YJ, Lee SH, Park HR, Korean J. Met. Mater., 51(1), 51 (2013)
Kwak YJ, Park HR, Song MY, Met. Mater. International, 19(3), 543 (2013)
Song MY, Kwon SN, Park HR, Korean J. Met. Mater., 51(6), 455 (2013)
Song My, Kwon SN, Mumm DR, Met. Mater. International, 19(2), 309 (2013)
Krozer A, Kasemo B, J. Phys. Condens. Matter, 1(8), 1533 (1989)
Stillesjoe F, Olafsson S, Hjoervarsson B, Karlsson E, Zeitschrift fur Physikalische Chemie, 181(1-2), 353 (1993)
Bobet JL, Akiba E, Nakamura Y, Darriet B, Int. J. Hydrog. Energy, 25, 987 (2000)
Huot J, Tremblay ML, Schulz R, J. Alloy. Compd., 356-357, 603 (2003)

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[2] Zaluska A, Zaluski L, Strom-Olsen JO, J. Alloy. Compd., 288, 217 (1999)

[3] Manchester FD, Khatamian D, Mater. Sci. Forum, 31, 261 (1988)

[4] Chen CP, Liu BH, Li ZP, Wu J, Wang QD, Zeitschrift fur Physikalische Chemie, 181(1-2), 259 (1993)

[5] Liang G, Wang E, Fang S, J. Alloy. Compd., 223(1), 111 (1995)

[6] Schlapbach L, Hydrogen in Intermetallic Compounds II. Surface and Dynamic Properties, Applications, Topics in Applied Physics. Springer, 1992, p. 671.

[7] Norskov JK, Houmoller A, Johansson PK, Lundqvist BI, Phys. Rev. Lett., 46(4), 257 (1981)

[8] Song MY, J. Mater. Sci., 30(5), 1343 (1995)

[9] Suryanarayana C, Prog. Mater. Sci., 46(1-2), 1 (2001)

[10] Stander C, Zeitschrift fur Physikalische Chemie, 104(4-6), 229 (1997)

[11] Stioui M, Grayevski A, Resnik A, Shaltiel D, Kaplan N, J. Less-Common Metals, 123, 9 (1986)

[12] Vigeholm B, Jensen K, Larsen B, Schroder-Pedersen A, J. Less-Common Metals, 131, 133 (1987)

[13] Kwak YJ, Park HR, Song MY, Korean J. Met. Mater., 50(11), 855 (2012)

[14] Song MY, Kwon SN, Hong SH, Park HR, Met. Mater. International, 18(2), 279 (2012)

[15] Kwak YJ, Lee SH, Park HR, Song MY, Korean J. Met. Mater., 51(8), 607 (2012)

[16] Song MY, Kwak YJ, Lee SH, Park HR, Korean J. Met. Mater., 51(8), 607 (2012)

[17] Song MY, Kwak YJ, Lee SH, Park HR, Korean J. Met. Mater., 51(1), 51 (2013)

[18] Kwak YJ, Park HR, Song MY, Met. Mater. International, 19(3), 543 (2013)

[19] Song MY, Kwon SN, Park HR, Korean J. Met. Mater., 51(6), 455 (2013)

[20] Song My, Kwon SN, Mumm DR, Met. Mater. International, 19(2), 309 (2013)

[21] Krozer A, Kasemo B, J. Phys. Condens. Matter, 1(8), 1533 (1989)

[22] Stillesjoe F, Olafsson S, Hjoervarsson B, Karlsson E, Zeitschrift fur Physikalische Chemie, 181(1-2), 353 (1993)

[23] Bobet JL, Akiba E, Nakamura Y, Darriet B, Int. J. Hydrog. Energy, 25, 987 (2000)

[24] Huot J, Tremblay ML, Schulz R, J. Alloy. Compd., 356-357, 603 (2003)