화학공학소재연구정보센터
홈 로그인 로그아웃 연락처 사이트맵
Journal of Industrial and Engineering Chemistry, Vol.21, 428-435, January, 2015
DOI10.1016/j.jiec.2014.03.001  Export Citation
Characterization of MIPA and DIPA aqueous solutions in relation to absorption, speciation and degradation
A.B. Lopez, M.D. La Rubia†, J.M. Navaza1, R. Pacheco, and D. Gomez-Dıaz1
  • Bioprocesos Research Team, Department of Chemical, Environmental and Materials Engineering, EPS, University of Jaen, Jaen, Andalucıa, Spain
  • 1PF&PT Research Team, Department of Chemical Engineering, ETSE, University of Santiago de Compostela, Santiago de Compostela, Galicia, Spain
E-mail:
The carbon dioxide absorption process by 1-amino-2-propanol (MIPA) and bis(2-hydroxypropyl)amine (DIPA) aqueous solutions in bubble column reactor have been studied considering the influence of liquid phase physical properties and the amine group substitution on the overall process. Themain objective of this work was to establish the carbon dioxide capture reaction mechanism for these systems, and then to obtain the predominant stoichiometry to calculate the mass transfer coefficient. NMR technique was used to determine the species present in the liquid phase during the absorption process and to confirm the reaction mechanism. The degradation of these amines was also evaluated.
Keywords:Carbon dioxide capture;Amine;Absorption;Degradation;NMR
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