화학공학소재연구정보센터
홈 로그인 로그아웃 연락처 사이트맵
Journal of Industrial and Engineering Chemistry, Vol.21, 507-515, January, 2015
DOI10.1016/j.jiec.2014.03.013  Export Citation
Fine-tuning mesoporous adsorbent for simultaneous ultra-trace palladium(II) detection, separation and recovery
Md. Rabiul Awual†, and Md. Munjur Hasan1
  • Actinide Coordination Chemistry Group, Quantum Beam Science Directorate, Japan Atomic Energy Agency (SPring–8), Hyogo 679–5148, Japan
  • 1Shaheed Ziaur Rahman Medical College, Bogra 5800, Bangladesh
E-mail:
A simple and sensitive method was applied for determination and extraction of trace level palladium(II) in wastewater by using functionalized mesoporous silica based fine-tuning mesoporous adsorbent. The adsorbent was stable and easy to detect, adsorb and recover Pd(II) ions by charge transfer (intense π-π transition) complexation mechanism. The optimum experimental conditions such as pH, contact time, initial concentration, selectivity and sensitivity, type and amount of eluent for elution and various ionic interferences on detection and sorption were systematically evaluated. The determined maximum sorption capacity was 191.35 mg/g. The proposed method was applied successfully for extraction of Pd(II) in environmental wastewater samples.
Keywords:Palladium(II);Detection and extraction;Mesoporous adsorbent;High selectivity;Uptake kinetics
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