Synthesis and characterization of ultrafine and mesoporous structure of cobalt ferrite

Hamid Emadi; Ali Nemati Kharat

Journal of Industrial and Engineering Chemistry, Vol.21, 951-956, January, 2015

DOI10.1016/j.jiec.2014.04.037 Export Citation

Synthesis and characterization of ultrafine and mesoporous structure of cobalt ferrite

Hamid Emadi, and Ali Nemati Kharat^†

School of Chemistry, University College of Science, University of Tehran, Tehran, Iran

E-mail:

Ultrafine nanoparticles of cobalt ferrite (CoFe2O4) were synthesized under microwave irradiation in polyol media and then were applied for the synthesis of mesoporous structures of cobalt ferrite. The effect of reaction parameters on products were investigated by X-ray diffraction (XRD), scanning electron microscopy (SEM), transmittance electron microscopy (TEM), energy dispersive X-ray spectroscopy (EDS), Fourier transform infrared (FT-IR) spectra, vibrating sample magnetometer (VSM), and volumetric nitrogen adsorption. TEM and BET analysis showed presence of mesoporus structures with pore sizes less than 10 nm in the final product.

Keywords:Nanoparticles;CoFe2O4;Microwave;Mesoporus structure;Electron microscopy

[References]

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[1] Ursache A, Goldbach JT, Russell TP, Tuominen MT, J. Appl. Phys., 97, 10322 (2005)

[2] Salavati-Niasari M, Banaiean-Monfared G, Emadi H, Enhessari M, C. R. Chim., 16, 929 (2013)

[3] Emadi H, Salavati-Niasari M, Superlattices Microstruct., 54, 118 (2013)

[4] Yang G, Tang J, Kato S, Zhang Q, Qin LC, Woodson M, Liu J, Kim JW, Littlehei PT, Park C, Zhou O, Appl. Phys. Lett., 87, 123507 (2005)

[5] Kruglyak VV, Hichen RJ, Kuchko AN, Gorobets VY, J. Appl. Phys., 98, 014304 (2005)

[6] Meng XJ, Cheng JG, Li B, Guo SL, Ye HJ, Chu JH, J. Cryst. Growth, 208(1-4), 541 (2000)

[7] Zheng H, Wang J, Lofland SE, Ma Z, Mohaddes-Ardabili L, Zhao T, Salamanca-Riba L, Shinde SR, Ogale SB, Bai F, Viehland D, Jia Y, Schlom DG, Wuttig M, Roytburd A, Ramesh R, Science, 303, 661 (2004)

[8] Huh YM, Jun YW, Song HT, Kim S, Choi JS, Lee JH, Yoon S, Kim KS, Shin JS, Suh JS, Cheon J, J. Am. Chem. Soc., 127(35), 12387 (2005)

[9] Song HT, Choi JS, Huh YM, Kim S, Jun YW, Suh JS, Cheon J, J. Am. Chem. Soc., 127(28), 9992 (2005)

[10] Batlle X, Labarta AD, J. Appl. Phys., 35, R15 (2002)

[11] Bean CP, Deblois RW, Nesbitt LB, J. Appl. Phys., 30, 1976 (1959)

[12] Wang W, Zhu F, Weng J, Xiao J, Lai W, Appl. Phys. Lett., 72, 1118 (1998)

[13] Dinega DP, Bawendi MG, Angew. Chem.-Int. Edit., 38, 1788 (1999)

[14] Sun S, Murray CB, J. Appl. Phys., 85, 4325 (1999)

[15] Singhal S, Barthwal SK, Chandra K, J. Magn. Magn. Mater., 306, 233 (2006)

[16] Niu ZP, Wang Y, Li FS, J. Mater. Sci., 41(17), 5726 (2006)

[17] Vasambekar PN, Kolekar CB, Vaingankar AS, Mater. Chem. Phys., 601, 282 (1999)

[18] Zhang F, Kantake S, Kitamoto Y, Abe M, IEEE Trans. Magn., 35, 2751 (1999)

[19] Pallai V, Shah DO, J. Magn. Magn. Mater., 163, 243 (1996)

[20] Skomski R, J. Phys. Condens. Matter, 15, R1 (2003)

[21] Cui H, Jia Y, Ren W, Wang W, J. Sol-Gel Sci. Technol., 55, 36 (2010)

[22] Gopalan EV, Joy PA, Al-Omari IA, Kumar DS, Yoshida Y, Anantharaman MR, J. Alloy. Compd., 485, 711 (2009)

[23] Goh SC, Chia CH, Zakaria S, Yusoff M, Haw CY, Ahmadi S, Huang NM, Lim HN, Mater. Chem. Phys., 120(1), 31 (2010)

[24] Richard PM, Yenny C, Vargas P, Silva J, Uwakweh ONC, Mater. Char., 61, 1317 (2010)

[25] Wang J, Tong D, Lin Y, Yang C, Zhan W, J. Alloy. Compd., 450, 532 (2008)

[26] Turtelli RS, Duong GV, Nunes W, Grossinger R, Knobel M, J. Magn. Magn. Mater., 320, e339 (2008)

[27] Yousefi M, Sabet M, Salavati-Niasari M, Emadi H, J. Clust. Sci., 23, 511 (2012)

[28] Jiang FY, Wang CM, Fu Y, Liu RC, J. Alloy. Compd., 503, L31 (2010)

[29] Ni Y, Mab X, Hongb J, Xu Z, Mater. Lett., 58, 2754 (2004)

[30] Emadi H, Kharat AN, Mater. Res. Bull., 48(10), 3994 (2013)

[31] Waldron RD, Phys. Rev., 99, 1727 (1955)

[32] Gao ZM, Wu TH, Peng SY, Acta Phys. Chim. Sin., 11, 395 (1995)

[33] Kurikka VPMS, Gedanken A, Chem. Mater., 10, 3445 (1998)

[34] Xiong G, Yu SJ, Yang XJ, J. Fouc. Maters, 29, 92 (1998)

[35] Nadeem K, Krenn H, Traussnig T, Wurschum R, Szabo DV, Letofsky-Papst I, J. Magn. Magn. Mater., 323, 1998 (2011)

[36] Kodama RH, Berkowitz AE, Phys. Rev. Lett., 77, 394 (1996)