화학공학소재연구정보센터
홈 로그인 로그아웃 연락처 사이트맵
Journal of Industrial and Engineering Chemistry, Vol.21, 1160-1166, January, 2015
DOI10.1016/j.jiec.2014.05.029  Export Citation
New synthetic mercaptoethylamino homopolymer-modified maghemite nanoparticles for effective removal of some heavy metal ions from aqueous solution
Tayyebeh Madrakian†, Abbas Afkhami, Borhan Zadpour, and Mazaher Ahmadi
  • Faculty of Chemistry, Bu-Ali Sina University, Faj av., Hamedan 6517838695, Iran
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A maghemite nanoparticles modified with homopolymers of a new mercaptoethylamino monomer (MAMNPs) have been prepared. The MAMNPs nanoparticles were fully characterized by FT-IR, XRD, BET and TEM measurements. The influences of parameters including pH, dosage of adsorbent and contact time have been investigated in order to find the optimum adsorption conditions. Metal ions adsorption process was thoroughly studied from both kinetic and equilibrium points of view. MAMNPs showed high tendency to investigated metal ions, in this order: Ag(I) > Hg(II) > Pb(II) > Cd(II), owing to the strong contribution of surface loaded polymer.
Keywords:Magnetic nanoparticles;Removal;Heavy metal ions;Polymer
  1. Khan NA, Hasan Z, Jhung SH, J. Hazard. Mater., 244-245, 444 (2013)
  2. Liu C, Huang Y, Naismith N, Economy J, Environ. Sci. Technol., 37, 4261 (2003)
  3. Ke F, Qiu LG, Yuan YP, Peng FM, Jiang X, Xie AJ, Shen YH, Zhu JF, J. Hazard. Mater., 196, 36 (2011)
  4. Madrakian T, Afkhami A, Ahmadi M, Chemosphere, 90, 542 (2013)
  5. Itskos G, Koukouzas N, Vasilatos C, Megremi I, Moutsatsou A, J. Hazard. Mater., 183(1-3), 787 (2010)
  6. Al-Othman ZA, Inamuddin, Naushad M, Chem. Eng. J., 171(2), 456 (2011)
  7. Ju XJ, Zhang SB, Zhou MY, Xie R, Yang L, Chu LY, J. Hazard. Mater., 167(1-3), 114 (2009)
  8. Tofighy MA, Mohammadi T, J. Hazard. Mater., 185, 140 (2011)
  9. Koukouzas N, Vasilatos C, Itskos G, Mitsis I, Moutsatsou A, J. Hazard. Mater., 173(1-3), 581 (2010)
  10. Moutsatsou A, Stamatakis E, Hatzitzotzia K, Protonotarios V, Fuel, 85(5-6), 657 (2006)
  11. Fu FL, Xie LP, Tang B, Wang Q, Jiang SX, Chem. Eng. J., 189-190, 283 (2012)
  12. Afkhami A, Saber-Tehrani M, Bagheri H, J. Hazard. Mater., 181(1-3), 836 (2010)
  13. Zhang LZ, Zhao YH, Bai RB, J. Membr. Sci., 379(1-2), 69 (2011)
  14. Madrakian T, Afkhami A, Ahmadi M, Bagheri H, J. Hazard. Mater., 196, 109 (2011)
  15. Ge F, Li MM, Ye H, Zhao BX, J. Hazard. Mater., 211-212, 366 (2012)
  16. Huang SH, Chen DH, J. Hazard. Mater., 163(1), 174 (2009)
  17. Bayramoglu G, Arica MY, J. Hazard. Mater., 144(1-2), 449 (2007)
  18. Afkhami A, Saber-Tehrani M, Bagheri H, Madrakian T, Microchim. Acta, 172, 125 (2011)
  19. Madrakian T, Afkhami A, Ahmadi M, Spectroc. Acta Pt. A-Molec. Biomolec. Spectr., 99, 102 (2012)
  20. Liao MH, Chen DH, Biotechnol. Lett., 24(22), 1913 (2002)
  21. Mak SY, Chen DH, Dyes Pigment., 61, 93 (2004)
  22. Chang YC, Chen DH, J. Colloid Interface Sci., 283(2), 446 (2005)
  23. Pham MT, Soo KK, J. Nanosci. Nanotechnol., 9, 905 (2009)
  24. Madrakian T, Ahmadi M, Afkhami A, Soleimani M, Analyst, 138, 4542 (2013)
  25. Madrakian T, Afkhami A, Mahmood-Kashani H, Ahmadi M, Talanta, 105, 255 (2013)
  26. Huang C, Hu B, Spectroc. Acta, 63, 437 (2008)
  27. Shishehbore MR, Afkhami A, Bagheri H, Chem. Cent. J., 5, 41 (2011)
  28. Hu J, Chen GH, Irene MC, Water Res., 39, 4528 (2005)
  29. Chang B, Sha X, Guo J, Jiao Y, Wang C, Yang W, J. Mater. Chem., 21, 9239 (2011)
  30. Li GL, Zhao ZS, Liu JY, Jiang GB, J. Hazard. Mater., 192(1), 277 (2011)
  31. Xin X, Wei Q, Yang J, Yan L, Feng R, Chen G, Du B, Li H, Chem. Eng. J., 184, 132 (2012)
  32. Machida M, Fotoohi B, Amamo Y, Ohba T, Kanoh H, Mercier L, J. Hazard. Mater., 221-222, 220 (2012)
  33. Madrakian T, Afkhami A, Rahimi M, Ahmadi M, Soleimani M, Talanta, 115, 468 (2013)
  34. Madrakian T, Afkhami A, Zolfigol MA, Ahmadi M, Koukabi N, Nano-Micro Lett., 4, 57 (2012)
  35. Brunauer S, Emmett PH, Teller E, J. Am. Chem. Soc., 60, 309 (1938)
  36. Singh S, Barick KC, Bahadur D, J. Hazard. Mater., 192(3), 1539 (2011)
  37. Lagergren S, Handlingar, 24, 1 (1898)
  38. Azizian S, J. Colloid Interface Sci., 276(1), 47 (2004)
  39. Zhou YT, Christopher BW, Nie HL, Colloids Surf. B: Biointerfaces, 74, 244 (2009)
  40. Lin YF, Chen HW, Chien PS, Chiou CS, Liu CC, J. Hazard. Mater., 185(2-3), 1124 (2011)
  41. Langmuir I, J. Am. Chem. Soc., 38, 2221 (1916)
  42. Freundlich H, Heller W, J. Am. Chem. Soc., 61, 2228 (1939)
  43. Redlich O, Peterson DL, J. Phys. Chem., 63, 1024 (1959)
  44. Sips R, J. Chem. Phys., 16, 490 (1948)
  45. Temkin MJ, Pyzhev V, Acta Physiochim. URSS, 12, 217 (1940)
  46. Choi M, Jang J, J. Colloid Interface Sci., 325(1), 287 (2008)
  47. Ge F, Li MM, Ye H, Zhao BX, J. Hazard. Mater., 211-212, 366 (2012)
  48. Ren Y, Abbood HA, He FB, Peng H, Huang KX, Chem. Eng. J., 226, 300 (2013)
  49. Mohammadi SZ, Afzali D, Pourtalebi D, Cent. Eur. J. Chem., 8, 662 (2010)
  50. Pan SD, Zhang Y, Shen HY, Hu MQ, Chem. Eng. J., 210, 564 (2012)
  51. Chen J, Qu RJ, Zhang Y, Sun CM, Wang CH, Ji CN, Yin P, Chen H, Niu YZ, Chem. Eng. J., 209, 235 (2012)
  52. Ma F, Qu RJ, Sun CM, Wang CH, Ji CN, Zhang Y, Yin P, J. Hazard. Mater., 172(2-3), 792 (2009)
  53. Fan LL, Luo CN, Lv Z, Lu FG, Qiu HM, J. Hazard. Mater., 194, 193 (2011)
  54. Huo HY, Su HJ, Tan TW, Chem. Eng. J., 150(1), 139 (2009)
  55. Yi Y, Wang YT, Liu H, Carbo, 53, 425 (2003)