Journal of Industrial and Engineering Chemistry, Vol.21, 1197-1207, January, 2015
Preparation of montmorillonite.alginate nanobiocomposite for adsorption of a textile dye in aqueous phase: Isotherm, kinetic and experimental design approaches
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In the present work, adsorption of basic red 46 (BR46) by nano-sized montmorillonite (MMT)/calcium alginate (CA) composite was optimized using central composite design. The maximum dye removal of 85.07% was obtained at an initial dye concentration of 30 mg L-1, adsorbent dosage of 2 g L-1, contact time of 60 min and temperature of 25 ℃. The adsorption capacity decreased with decreasing both initial pH and mixing speed. The pseudo-second order kinetic model had the highest correlation coefficient (R2 = 1.00). Based on the Langmuir isotherm model, the maximum adsorption capacity of MMT/CA was about 35 mg g-1.
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