습식 환원법에 의한 Ni 분말 합성시 반응조건의 영향

김동현; 박영민; 김이중; 진형호; 박홍채; 윤석영; Dong-Hyun Kim; Young-Min Park; Yi-Joong Kim; Hyeong-Ho Jin; Hong-Chae Park; Seog-Young Yoon

Korean Journal of Materials Research, Vol.14, No.10, 725-730, October, 2004

DOI10.3740/MRSK.2004.14.10.725 Export Citation

습식 환원법에 의한 Ni 분말 합성시 반응조건의 영향

The Effect of Reaction Conditions on the Preparation of Ni Powder Using Wet Chemical Reduction Process

김동현, 박영민, 김이중, 진형호, 박홍채 , 윤석영 ^†

부산대학교 재료공학부

Dong-Hyun Kim, Young-Min Park, Yi-Joong Kim, Hyeong-Ho Jin, Hong-Chae Park , and Seog-Young Yoon^†

School of Materials Science and Engineering, Pusan National University, Pusan 609-735, Korea

E-mail:

Nickel ultrafine powder have been synthesized by chemical reduction of aqueous NiSO 4 with hydrazine at various reaction conditions. The effect of reaction conditions such as the amount of surfactant and reductor, and reaction temperature on the particle size and shape was investigated by the mean of XRD, SEM and SEM-PSA. Experiments showed that the ratio of N 2 H 4 /Ni and the reaction temperature were affected on the particle size of the nickel powder. The average particle size of synthesized nickel powder increased with increasing reaction temperature regardless of the ratio of N 2 H 4 /Ni . Also the surfactant could influence the size and agglomeration of ultrafine powder with the reaction temperature.

Keywords:Ni powder;nickel sulfate;wet-reduction process;hydrazine hydrate;surfactant

[References]

Tseng WJ, Lin SY, Mater. Sci. Eng. A, 362, 160 (2003)
Park SH, Kim CH, Kang YC, Kim YH, J. Mater. Sci. Lett., 22(21), 1537 (2003)
Shoji H, Nakano Y, Matsushita H, Onoe A, Kanai H, Yamashita Y, J. Mater. Syn. Precess., 6, 415 (1998)
Herbrt JM, Trans. Br. Ceramic. Soc., 62(8), 645 (1963)
Herbrt JM, Proc. IEEE., 112(7), 144 (1965)
Yamamatsu J, Kawano N, Arashi T, Sato A, Nakano Y, Nomura T, J. of Powder Sources., 60, 199 (1996)
Degen A, Macek J, Nanostruct. Mater., 12, 225 (1999)
Tamir S, Berger S, Thin Solid Films, 276(1-2), 108 (1996)
Crane RA, Chao LC, Andres RP, Master. Res. Soc. Sympo. Proc., 368, 127 (1995)
Che S, Sakurai O, Yasuda T, Shinzaki K, Mizutami N, J. Ceram. Soc. Jpn., 105, 269 (1997)
Saguesa CD, Urbina RH, Figlarz M, Solid State Ionics., 63, 25 (1993)
Ueyama R, Ueyama R, Koumoto K, J. Ceram. Soc. of Japan., 110(4), 329 (2002)
Fievet F, Lagier JP, Blin B, Beaudoin B, Figlarz M, Solid State Ionics., 32-33, 198 (1989)
Ducamp-Sanguesa C, Herrera-Urbina R, Figlarz M, J. Solid State Chem., 100, 272 (1992)
Yu K, Kim DJ, Chung HS, Liang H, Materials Letter., 57, 3992 (2003)
Li YD, Wang CWHR, Li LQ, Qian YT, Mater. Chem. Phys., 59, 88 (1999)
LaMer VK, Dinger RH, J. Am. Chem. Soc., 72, 4847 (1950)
Statake I, Iwamatsu I, Bull. Chem. Soc. Jpn., 36, 204 (1962)
Piassa R, Pietro G, Europhys. Lett., 28, 445 (1994)
Aroson MP, Lanngmuir., 5, 494 (1989)
Anderson JR, Structure of Metallic Catalysts, Avademic Press, New York, 1975 (1975)
Hayter JB, Lenfold J, Colloid Polym. Sci., 261, 1022 (1983)

[Related Articles]

[1] Tseng WJ, Lin SY, Mater. Sci. Eng. A, 362, 160 (2003)

[2] Park SH, Kim CH, Kang YC, Kim YH, J. Mater. Sci. Lett., 22(21), 1537 (2003)

[3] Shoji H, Nakano Y, Matsushita H, Onoe A, Kanai H, Yamashita Y, J. Mater. Syn. Precess., 6, 415 (1998)

[4] Herbrt JM, Trans. Br. Ceramic. Soc., 62(8), 645 (1963)

[5] Herbrt JM, Proc. IEEE., 112(7), 144 (1965)

[6] Yamamatsu J, Kawano N, Arashi T, Sato A, Nakano Y, Nomura T, J. of Powder Sources., 60, 199 (1996)

[7] Degen A, Macek J, Nanostruct. Mater., 12, 225 (1999)

[8] Tamir S, Berger S, Thin Solid Films, 276(1-2), 108 (1996)

[9] Crane RA, Chao LC, Andres RP, Master. Res. Soc. Sympo. Proc., 368, 127 (1995)

[10] Che S, Sakurai O, Yasuda T, Shinzaki K, Mizutami N, J. Ceram. Soc. Jpn., 105, 269 (1997)

[11] Saguesa CD, Urbina RH, Figlarz M, Solid State Ionics., 63, 25 (1993)

[12] Ueyama R, Ueyama R, Koumoto K, J. Ceram. Soc. of Japan., 110(4), 329 (2002)

[13] Fievet F, Lagier JP, Blin B, Beaudoin B, Figlarz M, Solid State Ionics., 32-33, 198 (1989)

[14] Ducamp-Sanguesa C, Herrera-Urbina R, Figlarz M, J. Solid State Chem., 100, 272 (1992)

[15] Yu K, Kim DJ, Chung HS, Liang H, Materials Letter., 57, 3992 (2003)

[16] Li YD, Wang CWHR, Li LQ, Qian YT, Mater. Chem. Phys., 59, 88 (1999)

[17] LaMer VK, Dinger RH, J. Am. Chem. Soc., 72, 4847 (1950)

[18] Statake I, Iwamatsu I, Bull. Chem. Soc. Jpn., 36, 204 (1962)

[19] Piassa R, Pietro G, Europhys. Lett., 28, 445 (1994)

[20] Aroson MP, Lanngmuir., 5, 494 (1989)

[21] Anderson JR, Structure of Metallic Catalysts, Avademic Press, New York, 1975 (1975)

[22] Hayter JB, Lenfold J, Colloid Polym. Sci., 261, 1022 (1983)