Korean Journal of Materials Research, Vol.14, No.7, 462-469, July, 2004
지르코늄합금의 부식특성에 미치는 Cu 영향 평가
Evaluation of Cu Effect on Corrosion Characteristics of Zr Alloys
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The effect of Cu addition on the corrosion characteristics of Zr alloys that developed for nuclear fuel cladding in KAERI (Korea Atomic Energy Research Institute) was evaluated. The alloys having different element of Nb, Sn, Fe, Cr and Cu were manufactured and the corrosion tests of the alloys were performed in static autoclave at 360 ? C , distilled water condition. The alloys were also examined for their microstructures using the optical microscope and the TEM equipped with EDS and the oxide property was characterized by using X-ray diffraction. From the result of corrosion test more than 450 days, the corrosion rate of the Zr-based alloys was changed with alloying element such as Nb, Sn, Fe, Cr and especially affected by Cu addition. The corrosion resistance was increased with increasing the Cu content and the tetragonal ZrO 2 layer was more stabilized on the Cu-containing alloys.
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