조합화학을 이용한 CaO-Y 2 O 3 -Al 2 O 3 계의 Tb활성 형광체의 합성 및 검색

윤호신; 김창해; 강윤찬; 유승곤; 박희동; Ho Shin Yoon; Chang Hae Kim; Yun Chan Kang; Seung Kon Ryu; Hee Dong Park

Korean Journal of Materials Research, Vol.13, No.12, 785-790, December, 2003

DOI10.3740/MRSK.2003.13.12.785 Export Citation

조합화학을 이용한 CaO-Y 2 O 3 -Al 2 O 3 계의 Tb활성 형광체의 합성 및 검색

Combinatorial Synthesis and Screening of the Tb-activated Phosphors in the System CaO-Y 2 O 3 -Al 2 O 3

윤호신^†, 김창해¹, 강윤찬 ¹, 유승곤 , 박희동 ¹

충남대학교 화학공학과
¹한국화학연구원 화학소재연구부

Ho Shin Yoon^†, Chang Hae Kim¹, Yun Chan Kang¹, Seung Kon Ryu , and Hee Dong Park¹

Department of Chemical Engineering, Chungnam National University, Daeduk Science Town, Daejeon 305-764, Korea
¹Advanced Materials Division, Korea Research Insititute of Chemical Technology, Yusong, Daejeon 305-600, Korea

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We have synthesized some phosphors in the system CaO?Y 2 O 3 - Al 2 O 3 by combinatorial polymerized-complex method. Composition and synthetic temperature of phosphors in the library was screened from the emission intensities of individual samples under VUV excitation. In Tb 3+ -activated CaO?Y 2 O 3 - Al 2 O 3 , green phosphors showing good intensity were found to be X O 3 O 7 , CaYA1O 4 , YA1O 3 , Y 3 Al 5 O 12 , Y 4 A1 2 O 9 .?????

Keywords:Phosphor;Combinatorial Chemistry;CaYAl 3 O 7;CaYAlO 4

[References]

Danielson E, Golden JH, Mcfarland EW, Reaves CM, Weinberg WH, Wu XD, Nature, 389(6654), 944 (1997)
Sun XD, Wang KA, Yoo Y, WallaceFreedman WG, Gao C, Xiang XD, Schultz PG, Adv. Mater., 9(13), 1046 (1997)
Wang JS, Yoo Y, Gao C, Takeuchi I, Sun XD, Chang HY, Xiang XD, Schultz PG, Science, 279(5357), 1712 (1998)
McFarland EW, Weinberg WH, Trends in Biotechnology, 17, 107 (1999)
Xiang XD, Sun XD, Briceno G, Lou YL, Wang KA, Chang HY, Wallacefreedman WG, Chen SW, Schultz PG, Science, 268(5218), 1738 (1995)
Weidner JJ, Parlow JJ, Flynn DL, Tetrahedron Letter, 40, 239 (1999)
Kaldor SW, Siegel MG, Fritz JE, Dressman BA, Hahn PJ, Tetrahedron Letter, 37, 7193 (1996)
Pechini MP, Method of preparing Lead and Alkaline Earth Titanates and Miobates and Coating Method Using the Same to Form a Capacitor, U. S. Pat., (1967) (1967)
Morgan PED, Bump HA, Pugar EA, Ratto JJ, Oxy-Alkoxy Polymer Networks; Hench LL, Ulrich DR, Wiley, New York, (1986) (1986)
Kim CH, Park SM, Park JK, Park HD, Sohn KS, Park JT, J. Electrochem. Soc., 149, 12 (2002)
Koike J, KoJima T, Toyonaga R, Kagami A, Hase T, Inaho S, J. Electrochem. Soc., 126, 1008 (1979)
Shionoya S, Yen WM, Phosphor Handbook, CRC press, Boca Raton, FL (2000) (2000)
Jeon HS, Kim SK, Kim TW, Change SK, Jeong K, Choi JC, Park HL, Mater. Res. Bull., 35, 1477 (2000)
Sumida DS, Fan TY, Opt. Lett., 19, 1343 (1994)
Danielson, Golden E, MaFarland JH, Reaves EW, Weinberg CM, Wu WH, XD, 389, 944 (1997) (1997)
Park HD, Kim CH, Chang HC, Shon KS, Development of new phosphor materials though combinatorial chemistry and computed material design techniques, EL2002 (2002) (2002)
Van Uitert LG, Johnson LF, J. Chem. Phys., 44, 3514 (1966)
Blasse G, Philips Res. Repts., 22, 481 (1967)
Wybourne BG, Spectroscopic properties of rare earths, Interscience, New York (1965) (1965)
Jeon HS, Kim SK, Kim SC, Park SH, Park HL, Mho SI, Solid State Commun, 102(7), 555 (1997)
Robbins DJ, Cockayne B, Lent B, Glasper JL, Solid State Commu., 20, 673 (1976)
Van Der Weg MF, Popma JA, Vink AT, J. Appl. Phys., 57, 12 (1985)
Kakihana M, Okubo T, J. Alloys Compd., 266, 129 (1998)
Ter Heerdt MLH, Basun SA, Imbusch GF, Yen WM, J. Lumin., 100, 115 (2002)

[Related Articles]

[1] Danielson E, Golden JH, Mcfarland EW, Reaves CM, Weinberg WH, Wu XD, Nature, 389(6654), 944 (1997)

[2] Sun XD, Wang KA, Yoo Y, WallaceFreedman WG, Gao C, Xiang XD, Schultz PG, Adv. Mater., 9(13), 1046 (1997)

[3] Wang JS, Yoo Y, Gao C, Takeuchi I, Sun XD, Chang HY, Xiang XD, Schultz PG, Science, 279(5357), 1712 (1998)

[4] McFarland EW, Weinberg WH, Trends in Biotechnology, 17, 107 (1999)

[5] Xiang XD, Sun XD, Briceno G, Lou YL, Wang KA, Chang HY, Wallacefreedman WG, Chen SW, Schultz PG, Science, 268(5218), 1738 (1995)

[6] Weidner JJ, Parlow JJ, Flynn DL, Tetrahedron Letter, 40, 239 (1999)

[7] Kaldor SW, Siegel MG, Fritz JE, Dressman BA, Hahn PJ, Tetrahedron Letter, 37, 7193 (1996)

[8] Pechini MP, Method of preparing Lead and Alkaline Earth Titanates and Miobates and Coating Method Using the Same to Form a Capacitor, U. S. Pat., (1967) (1967)

[9] Morgan PED, Bump HA, Pugar EA, Ratto JJ, Oxy-Alkoxy Polymer Networks; Hench LL, Ulrich DR, Wiley, New York, (1986) (1986)

[10] Kim CH, Park SM, Park JK, Park HD, Sohn KS, Park JT, J. Electrochem. Soc., 149, 12 (2002)

[11] Koike J, KoJima T, Toyonaga R, Kagami A, Hase T, Inaho S, J. Electrochem. Soc., 126, 1008 (1979)

[12] Shionoya S, Yen WM, Phosphor Handbook, CRC press, Boca Raton, FL (2000) (2000)

[13] Jeon HS, Kim SK, Kim TW, Change SK, Jeong K, Choi JC, Park HL, Mater. Res. Bull., 35, 1477 (2000)

[14] Sumida DS, Fan TY, Opt. Lett., 19, 1343 (1994)

[15] Danielson, Golden E, MaFarland JH, Reaves EW, Weinberg CM, Wu WH, XD, 389, 944 (1997) (1997)

[16] Park HD, Kim CH, Chang HC, Shon KS, Development of new phosphor materials though combinatorial chemistry and computed material design techniques, EL2002 (2002) (2002)

[17] Van Uitert LG, Johnson LF, J. Chem. Phys., 44, 3514 (1966)

[18] Blasse G, Philips Res. Repts., 22, 481 (1967)

[19] Wybourne BG, Spectroscopic properties of rare earths, Interscience, New York (1965) (1965)

[20] Jeon HS, Kim SK, Kim SC, Park SH, Park HL, Mho SI, Solid State Commun, 102(7), 555 (1997)

[21] Robbins DJ, Cockayne B, Lent B, Glasper JL, Solid State Commu., 20, 673 (1976)

[22] Van Der Weg MF, Popma JA, Vink AT, J. Appl. Phys., 57, 12 (1985)

[23] Kakihana M, Okubo T, J. Alloys Compd., 266, 129 (1998)

[24] Ter Heerdt MLH, Basun SA, Imbusch GF, Yen WM, J. Lumin., 100, 115 (2002)