화학공학소재연구정보센터
Korean Journal of Materials Research, Vol.13, No.8, 514-518, August, 2003
유기 EL용 청색 발광 히드라존 유도체의 합성
Synthesis of Blue Emission Hydrazone Derivatives for Organic Electroluminescence
E-mail:
As a fundamental study on organic electroluminescence(EL), blue emitting materials were synthesized and characterized. Individual blue colored hydrazone derivatives were synthesized from the reaction of aldehydes (phthalaldehyde, isophthalaldehyde) with the corresponding amnios (1-methyl -1-phenylhydrazine, 1,1-diphenylhydrazine hydrochloride). Recrystallization of hydrazones from chloroform revealed the melting temperature within 142∼156 ? C . Photoluminescence(PL) analysis on each hydrazone showed that emission range were blue(458∼478 nm). The structure of obtained hydrazones were elucidated by FT-IR, 1 H-NMR and C, H, N elemental analyzer.
  1. Pope M, Kallmann HP, Magnate P, J. Chem. Phys., 38, 2042 (1962)
  2. Tang CW, VanSlyke SA, Appl. Phys. Lett., 51, 913 (1987)
  3. Burrows PE, Khalfin V, Gu G, Forrest SR, Appl. Phys. Lett., 73, 435 (1998)
  4. Gu G, Parthasarathy G, Forrest SR, Appl. Phys. Lett., 74, 305 (1999)
  5. Cumpston BH, Jensen KF, J. Appl. Polym. Sci., 69(12), 2451 (1998)
  6. Hamaguchi M, Yoshino K, Appl. Phys. Lett., 69, 143 (1996)
  7. Kim YK, Korean Information Display Society, 2, 6 (2001)
  8. Kwon SK, Korean Information Display Society, 4, 3 (2003)