GaOOH로부터 합성된 GaN 분말의 구조적, 광학적 특성

조성룡; 이종원; 박인용; 김선태; Sungryong Cho; Jongwon Lee; In Yong Park; Seontai Kim

Korean Journal of Materials Research, Vol.12, No.6, 476-481, June, 2002

DOI10.3740/MRSK.2002.12.6.476 Export Citation

GaOOH로부터 합성된 GaN 분말의 구조적, 광학적 특성

Structural and Optical Properties of GaN Powders Synthesized from GaOOH

조성룡, 이종원, 박인용, 김선태^†

한밭대학교 신소재공학부

Sungryong Cho, Jongwon Lee, In Yong Park, and Seontai Kim^†

Department of Materials Science & Engineering, Hanbat National University, Daejeon 305-719, Korea

E-mail:

In this work, we report on the synthesis of the GaN powders from gallium oxide hydroxide (GaOOH) powders and on the structural and optical properties of them. Simple heat treatment of GaOOH in the flow of NH 3 gas leads to the formation of submicron hexagonal GaN powders even at the low reaction temperature of 800 ? C . XRD measurements show that the powders obtained are the single phase GaN. EDS, FTIR, and PL measurements indicate the oxygen-associated characteristics. It is shown from the low temperature PL measurement on GaN powders synthesized at 1000 ? C that the shallow donor-acceptor recombination induced emission is more intense than the near band-edge excitonic emission.

Keywords:GaN;GaOOH;gallium;oxide;powder;photoluminescence

[References]

Mukai T, Nagahama S, Iwasa N, Senoh M, Yamada T, J. Phys. Condens. Matter, 13, 7089 (2001)
Craford MG, Stockman SA, Peanasky MJ, Kish FA, Semiconductors and Semimetals, Vol. 64, Electroluminescence (Editor, Mueller G), (Academic Press, San Diego, 2000) Chap. 1 (2000)
Balkas CM, Sitar Z, Bergman L, Shmagin IK, Muth JF, Kolbas R, Nemanich RJ, Davis RF, J. Cryst. Growth, 208(1-4), 100 (2000)
Kumar MS, Ramasamy P, Kumar J, J. Cryst. Growth, 211(1-4), 184 (2000)
Hara K, Matsuno Y, Matsuo Y, Jpn. J. Appl. Phys., 40, L242 (2001)
Millet P, Calka A, Williams JS, Vantenaar GJH, Appl. Phys. Lett., 63, 2505 (1993)
Li HD, Yang HB, Zou GT, Li YD, Liu SY, Yang SR, Appl. Phys. Lett, 69, 1285 (1996)
Isherwood BJ, Wickenden DK, J. Mater. Sci., 5, 869 (1970)
Kanie H, Sugimoto K, Okado H, Phys. Stat. Solidi. A, 188, 481 (2001)
Peng HY, Zhou XT, Wang N, Zheng YF, Liao LS, Shi WS, Lee CS, Lee ST, Chem. Phys. Lett., 327(5-6), 263 (2000)
Wood GL, Pruss EA, Paine RT, Chem. Mater., 13, 12 (2001)
Roy R, Hil VGl, Osborn EF, J. Am. Chem. Soc, 74, 719 (1952)
Almeida SA, Silva SRP, Sealy BJ, Watts JF, Thin Solid Films, 343-344, 632 (1999)
Baraton MI, Carlson G, Gonsalves KE, Mater. Sci. Eng. B, 50, 42 (1997)
Kubuki S, Nishida T, Kaung P, Yagi T, Maeda Y, J. Non-Cryst. Solids, 209, 87 (1997)
Bungaro C, Rapcewiez K, Bernhole J, Phys. Rev. B, 61, 6720 (2000)
Lagerstedt O, Monomar B, J. Appl Phys., 45, 2266 (1974)
Chen CC, Yeh CC, Chen CH, Yu MY, Liu HL, Wu JJ, Chen KH, Chen LC, Peng JY, Chen YF, J. Am. Chem. Soc., 123(12), 2791 (2001)
Varshni YP, Physica, 34, 149 (1967)
Li CF, Huang YS, Malikova L, Pollak FH, Phys. Rev. B, 55, 9251 (1997)

[Referenced By]

[1] Mukai T, Nagahama S, Iwasa N, Senoh M, Yamada T, J. Phys. Condens. Matter, 13, 7089 (2001)

[2] Craford MG, Stockman SA, Peanasky MJ, Kish FA, Semiconductors and Semimetals, Vol. 64, Electroluminescence (Editor, Mueller G), (Academic Press, San Diego, 2000) Chap. 1 (2000)

[3] Balkas CM, Sitar Z, Bergman L, Shmagin IK, Muth JF, Kolbas R, Nemanich RJ, Davis RF, J. Cryst. Growth, 208(1-4), 100 (2000)

[4] Kumar MS, Ramasamy P, Kumar J, J. Cryst. Growth, 211(1-4), 184 (2000)

[5] Hara K, Matsuno Y, Matsuo Y, Jpn. J. Appl. Phys., 40, L242 (2001)

[6] Millet P, Calka A, Williams JS, Vantenaar GJH, Appl. Phys. Lett., 63, 2505 (1993)

[7] Li HD, Yang HB, Zou GT, Li YD, Liu SY, Yang SR, Appl. Phys. Lett, 69, 1285 (1996)

[8] Isherwood BJ, Wickenden DK, J. Mater. Sci., 5, 869 (1970)

[9] Kanie H, Sugimoto K, Okado H, Phys. Stat. Solidi. A, 188, 481 (2001)

[10] Peng HY, Zhou XT, Wang N, Zheng YF, Liao LS, Shi WS, Lee CS, Lee ST, Chem. Phys. Lett., 327(5-6), 263 (2000)

[11] Wood GL, Pruss EA, Paine RT, Chem. Mater., 13, 12 (2001)

[12] Roy R, Hil VGl, Osborn EF, J. Am. Chem. Soc, 74, 719 (1952)

[13] Almeida SA, Silva SRP, Sealy BJ, Watts JF, Thin Solid Films, 343-344, 632 (1999)

[14] Baraton MI, Carlson G, Gonsalves KE, Mater. Sci. Eng. B, 50, 42 (1997)

[15] Kubuki S, Nishida T, Kaung P, Yagi T, Maeda Y, J. Non-Cryst. Solids, 209, 87 (1997)

[16] Bungaro C, Rapcewiez K, Bernhole J, Phys. Rev. B, 61, 6720 (2000)

[17] Lagerstedt O, Monomar B, J. Appl Phys., 45, 2266 (1974)

[18] Chen CC, Yeh CC, Chen CH, Yu MY, Liu HL, Wu JJ, Chen KH, Chen LC, Peng JY, Chen YF, J. Am. Chem. Soc., 123(12), 2791 (2001)

[19] Varshni YP, Physica, 34, 149 (1967)

[20] Li CF, Huang YS, Malikova L, Pollak FH, Phys. Rev. B, 55, 9251 (1997)