투명 유전체 (PbO-B 2 O 3 -SiO 2 -Al 2 O 3 계)와 Ag 전극과의 반응에 의한 Ag + 과 Sn 2+ 의 거동

홍경준; 박준현; 허증수; 김형순; Kyung Jun Hong; Jun Hyun Park; Jeung Soo Huh; Hyung Sun Kim

Korean Journal of Materials Research, Vol.12, No.5, 347-352, May, 2002

DOI10.3740/MRSK.2002.12.5.347 Export Citation

투명 유전체 (PbO-B 2 O 3 -SiO 2 -Al 2 O 3 계)와 Ag 전극과의 반응에 의한 Ag + 과 Sn 2+ 의 거동

Behavior of Ag + and Sn 2+ After Reaction Between the Transparent Dielectric PbO-B 2 O 3 -SiO 2 -Al 2 O 3 and Ag Electrodes

홍경준, 박준현¹, 허증수 , 김형순^{1, †}

경북대학교 공과대학 금속공학과
¹순천대학교 공과대학 재료·금속공학과

Kyung Jun Hong, Jun Hyun Park¹, Jeung Soo Huh , and Hyung Sun Kim^{1, †}

Dept. of Metall. Eng., Kyungpook National University, Korea
¹Dept. of Mat. Sci. and Metall. Eng., Sunchon National University, Korea

E-mail:

A transparent dielectric of the PbO?B 2 O 3 ?SiO 2 ?A1 2 O 3 system which was a low melting glass has been used for PDP (Plasma Display Panel), but it has a problem which is a reaction to be occurred between a transparent dielectric layer and electrodes (Ag, ITO) after firing. This research was conducted for ion migration of Ag + $and Sn^ {2+}duringfiringthreedifferentfritsoflowmeltingglass.Theresultshowedthatyellowingphenomenaoccurredthroughachemicalreactionbetween Ag^+\and Sn^ {2+}at550 58 0^{\circ}Cfor20 60min.Inaddition,itwasconfirmedthatthemigrationof Sn^{2+}$ from ITO electrode made a strong effect on the yellowing phenomena.

Keywords:PbO - B 2 O 3 - SiO 2 - Al 2 O 3 system;plasma display panel;transparent dielectric layer;Ag and ITO electrode;yellow phenomenon

[References]

Kim BK, J. Kor. Institute of Elect. and Elect. Mat. Eng., 13(8), 44 (2000)
Lee JY, Hong KJ, Kim DN, Kim HS, Huh JS, Korean J. Mater. Research, 11(305) (2001)
Masaki A, Katuyoshi Y, JP Patent, P2001-195989 (2001) (2001)
Park JH, 'Understanding of Plasma Display, 2nd,' (2001) 171. Jeil Pub. Pusan, Korea (2001)
Scholze H, Glass, Nature Struture, and Properties, 3rd., Springer-Verlag, New York, 185 (1991) (1991)
Kim TN , Lee JY, Kim HS, Huh JS, Korean Information Display Society, 1, 95 (2000)
Wang PW, Zhang LP, Lu L, LdMone DV, Kinse DL, Appl. Surf. Sci., 84, 75 (1995)
Owen AE, Phys. Chem. Glasses, 2, 87 (1961)
Lee KH, Choi SY, J. Kor. Ceram. Soc., 33, 242 (1996)
De Marchi G, Gonella F, Mazzoldi P, Battaglin G, Knystautas EJ, Meneghini C, J. Non-Cryst. Solids, 196, 79 (1996)
Yamane M, Shinata S, Yasumori A, Yano T, Takada H, J. Non-Cryst. Solids, 203, 268 (1996)
Yano T, Azegami K, Shibata S, Yamane M, J. Non-Cryst. Solids, 222, 94 (1997)
Wang PW, Appl. Surf. Sci., 120, 291 (1997)
Peters DP, Strohhofer C, Brongersma ML, van der Elsken J, Polman A, Nuclear Instruments and Methods in Physics Research B, 168, 237 (2000)
Takeda S, Akiyama R, Hosono H, J. Non-Cryst. Solids, 281, 1 (2001)
Takeda S, Yamamoto K, Matsumoto K, J. Non-Cryst. Solids, 265, 133 (2000)
Williams KFE, Johnson CE, Greengrass J, Tilley 3P, Gelder D, Johnson JA, J. Non-Cryst. Solids, 211, 164 (1997)
Williams KFE, Johnson CE, Nikolov O, Thomas MF, Johnson JA, Greengrass J, J. Non-Cryst. Solids, 242, 183 (1998)

[Related Articles]

[1] Kim BK, J. Kor. Institute of Elect. and Elect. Mat. Eng., 13(8), 44 (2000)

[2] Lee JY, Hong KJ, Kim DN, Kim HS, Huh JS, Korean J. Mater. Research, 11(305) (2001)

[3] Masaki A, Katuyoshi Y, JP Patent, P2001-195989 (2001) (2001)

[4] Park JH, 'Understanding of Plasma Display, 2nd,' (2001) 171. Jeil Pub. Pusan, Korea (2001)

[5] Scholze H, Glass, Nature Struture, and Properties, 3rd., Springer-Verlag, New York, 185 (1991) (1991)

[6] Kim TN , Lee JY, Kim HS, Huh JS, Korean Information Display Society, 1, 95 (2000)

[7] Wang PW, Zhang LP, Lu L, LdMone DV, Kinse DL, Appl. Surf. Sci., 84, 75 (1995)

[8] Owen AE, Phys. Chem. Glasses, 2, 87 (1961)

[9] Lee KH, Choi SY, J. Kor. Ceram. Soc., 33, 242 (1996)

[10] De Marchi G, Gonella F, Mazzoldi P, Battaglin G, Knystautas EJ, Meneghini C, J. Non-Cryst. Solids, 196, 79 (1996)

[11] Yamane M, Shinata S, Yasumori A, Yano T, Takada H, J. Non-Cryst. Solids, 203, 268 (1996)

[12] Yano T, Azegami K, Shibata S, Yamane M, J. Non-Cryst. Solids, 222, 94 (1997)

[13] Wang PW, Appl. Surf. Sci., 120, 291 (1997)

[14] Peters DP, Strohhofer C, Brongersma ML, van der Elsken J, Polman A, Nuclear Instruments and Methods in Physics Research B, 168, 237 (2000)

[15] Takeda S, Akiyama R, Hosono H, J. Non-Cryst. Solids, 281, 1 (2001)

[16] Takeda S, Yamamoto K, Matsumoto K, J. Non-Cryst. Solids, 265, 133 (2000)

[17] Williams KFE, Johnson CE, Greengrass J, Tilley 3P, Gelder D, Johnson JA, J. Non-Cryst. Solids, 211, 164 (1997)

[18] Williams KFE, Johnson CE, Nikolov O, Thomas MF, Johnson JA, Greengrass J, J. Non-Cryst. Solids, 242, 183 (1998)