Thermal and cure shrinkage behaviors of epoxy resins cured by thermal cationic catalysts

Soo-Jin Park; Gun-Young Heo; Fan-Long Jin

Macromolecular Research, Vol.23, No.2, 156-160, February, 2015

DOI10.1007/s13233-015-3028-y Export Citation

Thermal and cure shrinkage behaviors of epoxy resins cured by thermal cationic catalysts

Soo-Jin Park^{1, †}, Gun-Young Heo¹, and Fan-Long Jin^{1, 2}

¹Department of Chemistry, Inha University, 253 Nam-gu, Gyeonggi, 402-751, Korea
²Department of Polymer Materials, Jilin Institute of Chemical Technology, Jilin City, 132022, P. R. China

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The thermal and volumetric change properties of diglycidyl ether of bisphenol A (DGEBA) epoxy resin were studied using two thermal cationic catalysts: benzylquinoxalinium hexafluoroantimonate (BQH) and triphenyl benzyl phosphonium hexafluoroantimonate (TBPH). The cure reactivity and thermal stability of the DGEBA/BQH system were higher than those of the DGEBA/TBPH system; this was because of the slow thermal diffusion rate of the DGEBA/TBPH system induced by the bulky phenyl groups in TBPH. The volumetric change values of DGEBA/BQH and DGEBA/TBPH were -0.17% and 7.95%, respectively.

Keywords:epoxy resin;thermal cationic catalyst;cure reactivity;thermal stability;volumetric change

[References]

May CA, Epoxy Resins: Chemistry and Technology. Marcel Dekker, New York (1988)
Gu L, Chen G, Yao Y, Polym. Degrad. Stab., 108, 68 (2014)
Sudo A, Isobe Y, Endo T, J. Appl. Polym. Sci., 112(2), 836 (2009)
Thomason JL, Yang L, Compos. Sci. Technol., 96, 7 (2014)
Heo GY, Park SJ, Macromol. Res., 17(11), 870 (2009)
Billotte C, Bernard FM, Ruiz E, Eur. Polym. J., 49, 3548 (2013)
Bailey WJ, Polym. Symp., 64, 17 (1978)
Sangermano M, Ortiz RA, Puente BA, Berlanga ML, Garcia AE, Guerrero R, Eur. Polym. J., 44, 1046 (2008)
Ortiz RA, Savage AG, Berlanga ML, Sangermano M, Garcia AE, Polym. Int., 59, 680 (2010)
Ishida H, Low HY, Macromolecules, 30(4), 1099 (1997)
Parlevliet PP, Bersee HEN, Beukers A, Polym. Test., 29, 433 (2010)
Liu J, Agag T, Ishida H, Polymer, 51(24), 5688 (2010)
Rimdusit S, Kampangsaeree N, Tanthapanichakoon W, Takeichi T, Suppakarn N, Polym. Eng. Sci., 47(2), 140 (2007)
Chernykh A, Agag T, Ishida H, Polymer, 50(2), 382 (2009)
Park SJ, Heo GY, Suh DH, J. Polym. Sci. A: Polym. Chem., 41(15), 2393 (2003)
Flores M, Fernandez-Francos X, Morancho JM, Serra A, Ramis X, Thermochim. Acta, 543, 188 (2012)
Park SJ, Jin FL, Polym. Degrad. Stab., 86, 515 (2004)
Dong W, Liu HC, Park SJ, Jin FL, J. Ind. Eng. Chem., 20(4), 1220 (2014)
Park SJ, Jin FL, Lee JR, Shin JS, Eur. Polym. J., 41, 231 (2005)
Park SJ, Jin FL, Lee JR, Macromol. Rapid Commun., 25(6), 724 (2004)
Holst M, Schanzlin K, Wenzel M, Xu JJ, Lellinger D, Alig I, J. Polym. Sci. B: Polym. Phys., 43(17), 2314 (2005)
Yu H, Mhaisalkar S, Wong E, J. Electron. Mater., 34, 1177 (2005)
Meure S, Wu DY, Furman SA, Vib. Spectrosc., 52, 10 (2010)
Fraga F, Vazquez EC, Rodriguez-Nunez E, Martinez-Ageitos JM, Polym. Adv. Technol., 19, 1623 (2008)
Park SJ, Jin FL, Lee JR, Macromol. Chem. Phys., 205, 2048 (2004)
Park SJ, Jin FL, Lee JR, Mater. Sci. Eng. A, 374, 109 (2004)
Heo GY, Park SJ, Macromol. Chem. Phys., 206, 1134 (2005)
Hsu SH, Chen RS, Chang YL, Chen MH, Cheng KC, Su WF, Acta Biomater., 8, 4151 (2012)

[Related Articles]

[1] May CA, Epoxy Resins: Chemistry and Technology. Marcel Dekker, New York (1988)

[2] Gu L, Chen G, Yao Y, Polym. Degrad. Stab., 108, 68 (2014)

[3] Sudo A, Isobe Y, Endo T, J. Appl. Polym. Sci., 112(2), 836 (2009)

[4] Thomason JL, Yang L, Compos. Sci. Technol., 96, 7 (2014)

[5] Heo GY, Park SJ, Macromol. Res., 17(11), 870 (2009)

[6] Billotte C, Bernard FM, Ruiz E, Eur. Polym. J., 49, 3548 (2013)

[7] Bailey WJ, Polym. Symp., 64, 17 (1978)

[8] Sangermano M, Ortiz RA, Puente BA, Berlanga ML, Garcia AE, Guerrero R, Eur. Polym. J., 44, 1046 (2008)

[9] Ortiz RA, Savage AG, Berlanga ML, Sangermano M, Garcia AE, Polym. Int., 59, 680 (2010)

[10] Ishida H, Low HY, Macromolecules, 30(4), 1099 (1997)

[11] Parlevliet PP, Bersee HEN, Beukers A, Polym. Test., 29, 433 (2010)

[12] Liu J, Agag T, Ishida H, Polymer, 51(24), 5688 (2010)

[13] Rimdusit S, Kampangsaeree N, Tanthapanichakoon W, Takeichi T, Suppakarn N, Polym. Eng. Sci., 47(2), 140 (2007)

[14] Chernykh A, Agag T, Ishida H, Polymer, 50(2), 382 (2009)

[15] Park SJ, Heo GY, Suh DH, J. Polym. Sci. A: Polym. Chem., 41(15), 2393 (2003)

[16] Flores M, Fernandez-Francos X, Morancho JM, Serra A, Ramis X, Thermochim. Acta, 543, 188 (2012)

[17] Park SJ, Jin FL, Polym. Degrad. Stab., 86, 515 (2004)

[18] Dong W, Liu HC, Park SJ, Jin FL, J. Ind. Eng. Chem., 20(4), 1220 (2014)

[19] Park SJ, Jin FL, Lee JR, Shin JS, Eur. Polym. J., 41, 231 (2005)

[20] Park SJ, Jin FL, Lee JR, Macromol. Rapid Commun., 25(6), 724 (2004)

[21] Holst M, Schanzlin K, Wenzel M, Xu JJ, Lellinger D, Alig I, J. Polym. Sci. B: Polym. Phys., 43(17), 2314 (2005)

[22] Yu H, Mhaisalkar S, Wong E, J. Electron. Mater., 34, 1177 (2005)

[23] Meure S, Wu DY, Furman SA, Vib. Spectrosc., 52, 10 (2010)

[24] Fraga F, Vazquez EC, Rodriguez-Nunez E, Martinez-Ageitos JM, Polym. Adv. Technol., 19, 1623 (2008)

[25] Park SJ, Jin FL, Lee JR, Macromol. Chem. Phys., 205, 2048 (2004)

[26] Park SJ, Jin FL, Lee JR, Mater. Sci. Eng. A, 374, 109 (2004)

[27] Heo GY, Park SJ, Macromol. Chem. Phys., 206, 1134 (2005)

[28] Hsu SH, Chen RS, Chang YL, Chen MH, Cheng KC, Su WF, Acta Biomater., 8, 4151 (2012)