The impacts of hydrothermal aging on the selective catalytic reduction (SCR) performance of both Cu-SSZ-13 and Cu-SAPO-34 were compared. Upon 750 degrees C hydrothermal aging for 16 h, the NO conversions on both materials were somewhat maintained, however, a significant difference appeared after hydrothermal aging at 800 degrees C. The Cu-SSZ-13 sample resulted in remarkably lower NO conversions at all temperatures tested while the Cu-SAPO-34 still maintained its high SCR activity. In fact, the NO conversions at low temperatures (below 350 degrees C) over Cu-SAPO-34 were even enhanced upon high temperature treatment, suggesting an increase in active sites, which is possibly due to a post solid state ion exchange process driven by high temperatures. Consistently, for the Cu-SAPO-34 sample, NH3-TPD results suggest an increase in Lewis acid sites after hydrothermal aging at 750 and 800 degrees C as compared with the fresh one. However, for the Cu-SSZ-13 sample, DRIFTs characterization results suggest a decrease in acid sites (Bronsted and Lewis), and a significant reduction in the amount of exchanged Cu2+ sites upon aging at 800 degrees C, leading to a drastically decreased SCR activity. XRD results also showed the CHA (chabazite) structure collapses for Cu-SSZ-13 after 800 C hydrothermal aging of Cu-SSZ-13, but still remains for Cu-SAPO-34 upon the same aging. Besides SCR performance, critical functions of the SCR catalyst including NH3 oxidation activity and selectivity to NOx, were also evaluated. Over Cu-SSZ-13, initial aging at 750 degrees C results in increased NH3 oxidation and selectivity to NOx, suggesting the aggregation of isolated Cu2+ sites into CuO particles, while further aging at 800 degrees C leads to decreased NH3 oxidation activity due to structure collapse as evidenced by XRD. On the other hand, for Cu-SAPO-34, no significant change in NH3 oxidation was observed after hydrothermal aging. All SCR performance test, NH3 oxidation and characterization results consistently indicate that Cu-SAPO-34 is more robust than Cu-SSZ-13 towards hydrothermal aging for the formulations and conditions examined here. (C) 2014 Elsevier B.V. All rights reserved.