Semiconductor-based photocatalysts for solar H-2 generation has attracted significant attention because of its great potential for low-cost and clean H-2 production. In this study, we prepared a core-shell structured Au@CdS on TiO2 nanofibers (Au@CdS/TNF) and investigated its photocatalytic H-2 production under visible (lambda > 420 nm) irradiation. Photocatalysts, includingAu-deposited CdS/TNF (Au/CdS/TNF) and commercially available TiO2 (P25) instead of TNF, were investigated to determine the effect of a core-shell structured Au@CdS and the role of the TNF. Compared with CdS/TNF and Au/CdS/TNF, the Au@CdS/TNF exhibited strongly enhanced H-2 production under visible irradiation. Furthermore, H-2 production on Au@CdS/TNF was significantly enhanced compared to Au@CdS/P25. These results can be attributed to the synergistic effect of the core-shell structured Au@CdS and the compact structure of TNF. The core-shell structured Au@CdS may inhibit the formation of CdSO4 from CdS and the Au core could transfer electrons from CdS to TiO2 without any screening effect for light absorption by CdS. Moreover, interparticle electron transfer is more favorable for TNF than P25 due to the well-aligned TNF framework. This work demonstrates the synergistic effects of TiO2-based photocatalysts for the improvement of solar H-2 production efficiency. (C) 2014 Elsevier B.V. All rights reserved.