화학공학소재연구정보센터
Applied Surface Science, Vol.320, 620-626, 2014
Growth of SiC nanowires on wooden template surface using molten salt media
This paper examines the growth of SiC nanowires on a wooden template surface through the reaction of wooden template/silicon composites in static argon atmosphere, using molten salt media. The effects of temperature and salt/Si ratio on the growth of wooden template were investigated. Morphology and structure of the biomorphic SiC/C ceramics were characterized by X-ray diffraction (XRD), transmission electron microscopy (TEM), scanning electron microscopy (SEM) and thermogravimetric analysis (TGA). The pore size distribution within the porous SiC/C ceramics was investigated using automatic mercury porosimetry. The results show that the biomorphic cellular morphology of wooden template was remained in the porous SiC ceramic with high precision that consists of p-sic with traces of ce.-SiC. SiC in the wooden template exists in the cellular pores in the form of nanowires. The SiC nanowires were formed at about 1250 degrees C by molten salt reaction between Si and C during the wooden-to-ceramic conversion. Crown Copyright (C) 2014 Published by Elsevier B.V. All rights reserved.