ZnCdO is a promising partner of ZnO to form ZnO/ZnCdO heterojunction and quantum wells. High-quality Zn1-xCdxO (0 <= x <= 9.60 at.%) films have been grown on c-plane sapphire substrates by pulsed laser deposition. XRD pattern confirmed all the ZnCdO films are of single hexagonal phase oriented along c-axis. A band gap of 2.949 eV at room temperature has been achieved. The relation between band gap of Zn1-xCdxO system and Cd content x was expressed by E-g(x)= 1.023 x 10(-4) x(2) -0.034x + 3.253 (0 at.% <= x <= 100 at.%) according to the corrected first principles calculations. Furthermore, band offsets of ZnO/Zn(1-)xCd(x)O (x = 9.60 at.%) heterojunction were characterized by X-ray photoelectron spectroscopy and valence-band offset of 0.203 eV was measured. A conduction-band offset of approximately 0.110 eV could be inferred from the measured valence-band offset. It is found that a type-I alignment takes place at the interface. The accurate determination of the band alignment of ZnO/Zn1-xCdxO heterojunction facilitates the design of optical and electronic devices based on ZnO/Zn1-xCdxO. (C) 2014 Elsevier B.V. All rights reserved.