화학공학소재연구정보센터
Journal of Electroanalytical Chemistry, Vol.381, No.1-2, 99-104, 1995
Ohmic Distortion of Current-Potential Curves at Wall-Jet Electrodes
The ohmic distortion of current-voltage curves for the wall-jet hydrodynamic electrode is investigated using a finite-element approach with the circuit analysis program SPICE. Simulated and experimental data are presented, showing the displacement of the half-wave potential and the potential-dependent error in the Tafel slope. Error curves are given as a guide to the maximum current levels which may be used in practice with different electrolyte concentrations.