Co4N/gamma-Al2O3 and Co/gamma-Al2O3 catalysts with different metal loadings were prepared by NH3 and H-2-temperature programmed reaction method for the co-methanation of carbon oxides (CO and CO2). The catalysts were characterized by N-2 adsorption-desorption, XRD, XPS, TEM-SAED, H-2, CO, and CO2-TPD techniques. Results showed that the Co4N catalysts had higher activity than Co metal-supported catalysts due to their enhanced adsorption capacity, uniform metal dispersion, and superior metal-support interaction. Among the catalysts studied, 20Co(4)N/gamma-Al2O3 catalyst with 20 wt% metal loading showed the best performance. This catalyst achieved higher activity for CH4 formation between 200 and 300 degrees C and maintained high product selectivity (>= 98%). A 250 h stability test for 20Co(4)N/gamma-Al2O3 was also conducted at 350 degrees C and increased gas hourly space velocity (GHSV; 10,000 h(-1)). The spent catalyst was further characterized using XRD, TEM, and TGA analysis. Results revealed that the catalyst was highly resistant to metal sintering and carbon deposition, whereas high CO and CO2 conversion and CH4 selectivity were maintained even at a higher GHSV. (C) 2014 Elsevier B.V. All rights reserved.