화학공학소재연구정보센터
Chemical Engineering Science, Vol.122, 78-85, 2015
Enhanced carbon dioxide hydrate formation kinetics in a fixed bed reactor filled with metallic packing
In this fundamental work, two nonporous metallic (SS-316) mesh arrangements having high thermal conductivity compared to silica sand and silica gel were used as a packing material in a fixed bed setup for faster hydrate growth kinetics. Induction time and kinetics of carbon dioxide hydrate formation was investigated at 3.0 MPa and 274.65 K. An anionic surfactant, 1 wt% sodium dodecyl sulfate (SDS) was used as a kinetic promoter in all the experiments. Significantly higher gas uptake rate of 115 mol min(-1) min(-3) and water to hydrate conversion of 50% was achieved in an hour of hydrate formation with metallic packing in the presence of SDS. Amount of CO2 gas captured per mass/volume of packing material was significantly higher for metallic packing compared to silica sand and silica gel, which is an important parameter for evaluating a hydrate crystallization process using fixed bed. (C) 2014 Elsevier Ltd. All rights reserved.