화학공학소재연구정보센터
Journal of Chemical Thermodynamics, Vol.79, 272-279, 2014
Thermodynamic study of selected monoterpenes II
A thermodynamic study of selected monoterpenes, (-)-borneol, (-)-camphor, (+/-)-camphene, and (+/-)-fenchone is presented in this work. The vapor pressure measurements were performed using the static method over the environmentally important temperature range from (238 to 308) K. Heat capacities of condensed phases were measured by Tian-Calvet calorimetry in the temperature interval from (258 to 355) K. The phase behavior was investigated by differential scanning calorimetry (DSC) from subambient temperatures up to the fusion temperatures. The thermodynamic properties in the ideal-gas state were calculated by combining statistical thermodynamic and density functional theory (DFT) calculations. Calculated ideal-gas heat capacities and experimental data for vapor pressures and condensed phase heat capacities were treated simultaneously to obtain a consistent thermodynamic description. (C) 2013 Elsevier Ltd. All rights reserved.