Journal of Colloid and Interface Science, Vol.443, 88-96, 2015
Aqueous based synthesis of antimicrobial-decorated graphene
Ramizol (R) (1,3,5-tris[(1E)-2'-(4'-benzoic acid)vinyl]benzene) is a potent amphiphilic anti-microbial agent. It is essentially a planar molecule and can interact with the surface of graphene via extended pi-pi interactions. Herein we demonstrate the utility of Ramizol (R) in potentially acting as a molecular 'wedge' to exfoliate graphene and stabilise it in water. The non-covalent attachment of Ramizol (R) on the graphene surface enables release of Ramizol (R) by altering the pH of the solution. Furthermore, the stabilised composite material demonstrates antibacterial activity against Staphylococcus aureus which leads to potential in biomedical applications with graphene acting as a drug carrier as well as enhancing the structural strength of the composite material. (C) 2014 Elsevier Inc. All rights reserved.
Keywords:Graphene;Exfoliation;Ramizol;Ultra-sonication;Non-covalent functionalization;Antibacterial;Antimicrobial