화학공학소재연구정보센터
Progress in Energy and Combustion Science, Vol.37, No.5, 583-610, 2011
Advances and challenges in the development of power-generation systems at small scales
The miniaturization of electro-mechanical devices, and the resulting need for micro-power generation (milliwatts to watts) with low weight, long life devices, has lead to the recent development of the field of micro-scale combustion and power generation. The primary objective of this new field is to leverage the high energy density of fuels, specifically liquid hydrocarbon fuels relative to batteries and all other energy storage devices other than nuclear fission, fusion or decay. As such, a miniaturized device even with a moderately efficient conversion of hydrocarbon fuels to power would result in increased lifetime and/or reduced weight of an electronic or mechanical system that are currently most often powered by electrochemical cells. Furthermore, improvements in this field may make possible novel applications and/or capability. In addition to the interest in miniaturization, the field is also driven by the potential fabrication of the devices using Micro-Electro-Mechanical Systems (MEMS) or rapid prototyping techniques, with their favorable characteristics for mass production and/or low unit cost. The micro-power generation field is very young, and still is in most cases in the feasibility stage. However, considering that it is a new frontier of technological development, and that only a few projects have been funded, it can be said that significant progress has been made to date. Currently there is consensus, at least among those working in the field, that combustion at the micro-scale is possible with proper thermal and chemical management. Several meso-scale and micro-scale combustors have been developed that appear to operate with good combustion efficiency. Some of these combustors have been applied to energize thermoelectric systems to produce power, although with low overall efficiency. Several turbines/engines have also been, or are being, developed, some of them currently producing positive power, albeit with low efficiency. Micro-rockets using solid or liquid fuels have been built and shown to produce thrust. More detailed scaling/modeling efforts are required to improve existing designs. Improvements in diagnostic, control and computational tools are expected to have a significant impact on the development of the field. Some brief scaling arguments are given in this work, and more detailed efforts are referred. A brief introduction to several of the fabrication techniques is presented in this work. Hydrogen-based and some preliminary specialty fuel micro-fuel cells have been successfully developed, and there is a need to develop reliable reformers (or direct conversion fuel cells) for liquid hydrocarbons so that the fuel cells become competitive with the batteries. In this work, the technological issues related to micro-scale combustion and the development of thermochemical devices for power generation will be discussed. Some of the systems currently being developed will be presented, ongoing critical research issues under investigation, and other potential areas of development discussed. Comments regarding the opportunities and limitations of each of the techniques are also presented where applicable. (C) 2010 Elsevier Ltd. All rights reserved.